Rheological study and printability investigation of titania inks for direct ink writing process

Titanium dioxide is widely used in numerous industries and with the newly developed titanium manufacturing technique, referred to as the Near-net-shape Electrochemical Metallisation (NEM) Process, the rapid and precise production of titanium dioxide components is highly sought-after. This manuscript...

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Main Authors: Dolganov, Aleksei, Bishop, Matthew T., Chen, George Z., Hu, Di
Format: Article
Language:English
Published: Elsevier Ltd 2021
Subjects:
Online Access:https://eprints.nottingham.ac.uk/65183/
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author Dolganov, Aleksei
Bishop, Matthew T.
Chen, George Z.
Hu, Di
author_facet Dolganov, Aleksei
Bishop, Matthew T.
Chen, George Z.
Hu, Di
author_sort Dolganov, Aleksei
building Nottingham Research Data Repository
collection Online Access
description Titanium dioxide is widely used in numerous industries and with the newly developed titanium manufacturing technique, referred to as the Near-net-shape Electrochemical Metallisation (NEM) Process, the rapid and precise production of titanium dioxide components is highly sought-after. This manuscript presents the rheological investigation and extrudability tests of titania inks, to establish the improved production of titanium dioxide components via Direct Ink Writing. The extrudability tests indicated that despite an unfavourable increase in viscosity during the high shear rates (dilatancy peaks), the best-performing ink had a weight ratio of 1:0.8:0.1 TiO2:H2O:PEG, and the dilatancy peaks were smoothed out with the addition of 0.1 wt ratio of oleic acid to the ink, dramatically improving the quality of the product. To further improve the green bodies a new printing approach was also introduced, removing the necessity for specialised printing bed, by printing a removable support into the green body and allowing for drying without any cracks and warping.
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spelling nottingham-651832021-05-07T09:07:12Z https://eprints.nottingham.ac.uk/65183/ Rheological study and printability investigation of titania inks for direct ink writing process Dolganov, Aleksei Bishop, Matthew T. Chen, George Z. Hu, Di Titanium dioxide is widely used in numerous industries and with the newly developed titanium manufacturing technique, referred to as the Near-net-shape Electrochemical Metallisation (NEM) Process, the rapid and precise production of titanium dioxide components is highly sought-after. This manuscript presents the rheological investigation and extrudability tests of titania inks, to establish the improved production of titanium dioxide components via Direct Ink Writing. The extrudability tests indicated that despite an unfavourable increase in viscosity during the high shear rates (dilatancy peaks), the best-performing ink had a weight ratio of 1:0.8:0.1 TiO2:H2O:PEG, and the dilatancy peaks were smoothed out with the addition of 0.1 wt ratio of oleic acid to the ink, dramatically improving the quality of the product. To further improve the green bodies a new printing approach was also introduced, removing the necessity for specialised printing bed, by printing a removable support into the green body and allowing for drying without any cracks and warping. Elsevier Ltd 2021-05-01 Article PeerReviewed application/pdf en cc_by https://eprints.nottingham.ac.uk/65183/1/output%20%284%29.pdf Dolganov, Aleksei, Bishop, Matthew T., Chen, George Z. and Hu, Di (2021) Rheological study and printability investigation of titania inks for direct ink writing process. Ceramics International, 47 (9). pp. 12020-12027. ISSN 02728842 Rheology; Titanium dioxide; Titania; Direct ink writing http://dx.doi.org/10.1016/j.ceramint.2021.01.045 doi:10.1016/j.ceramint.2021.01.045 doi:10.1016/j.ceramint.2021.01.045
spellingShingle Rheology; Titanium dioxide; Titania; Direct ink writing
Dolganov, Aleksei
Bishop, Matthew T.
Chen, George Z.
Hu, Di
Rheological study and printability investigation of titania inks for direct ink writing process
title Rheological study and printability investigation of titania inks for direct ink writing process
title_full Rheological study and printability investigation of titania inks for direct ink writing process
title_fullStr Rheological study and printability investigation of titania inks for direct ink writing process
title_full_unstemmed Rheological study and printability investigation of titania inks for direct ink writing process
title_short Rheological study and printability investigation of titania inks for direct ink writing process
title_sort rheological study and printability investigation of titania inks for direct ink writing process
topic Rheology; Titanium dioxide; Titania; Direct ink writing
url https://eprints.nottingham.ac.uk/65183/
https://eprints.nottingham.ac.uk/65183/
https://eprints.nottingham.ac.uk/65183/