Molecular Simulations of Porous Solids for Adsorption Applications

The separation of gaseous mixtures plays a significant role across environmental, commercial, medicinal and analytical applications. In recent years, the emergence of metal-organic and covalent-organic frameworks has created a lot of attention within the material science community due to the versati...

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Main Author: Glover, Joseph
Format: Thesis (University of Nottingham only)
Language:English
English
Published: 2021
Subjects:
Online Access:https://eprints.nottingham.ac.uk/64401/
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author Glover, Joseph
author_facet Glover, Joseph
author_sort Glover, Joseph
building Nottingham Research Data Repository
collection Online Access
description The separation of gaseous mixtures plays a significant role across environmental, commercial, medicinal and analytical applications. In recent years, the emergence of metal-organic and covalent-organic frameworks has created a lot of attention within the material science community due to the versatile and highly tunable range of attractive physical and chemical properties that they possess. Due to the exceptionally large design space of these materials, it is often infeasible to synthesise and test each new material. Therefore, the viability of these materials for gas storage and separation applications is often predicted from computational modelling tools that can accurately characterise and assess the performance from molecular models of the adsorbent and adsorbates. In this thesis, different computational tool kits are employed to accurately characterise the structural properties of these materials and design a high-throughput protocol that can efficiently screen thousands of materials for membrane-based separations. The results may ultimately help the future design of novel membranes by providing relationships between the best performing materials and their structural design.
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format Thesis (University of Nottingham only)
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English
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publishDate 2021
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spelling nottingham-644012025-02-28T15:10:44Z https://eprints.nottingham.ac.uk/64401/ Molecular Simulations of Porous Solids for Adsorption Applications Glover, Joseph The separation of gaseous mixtures plays a significant role across environmental, commercial, medicinal and analytical applications. In recent years, the emergence of metal-organic and covalent-organic frameworks has created a lot of attention within the material science community due to the versatile and highly tunable range of attractive physical and chemical properties that they possess. Due to the exceptionally large design space of these materials, it is often infeasible to synthesise and test each new material. Therefore, the viability of these materials for gas storage and separation applications is often predicted from computational modelling tools that can accurately characterise and assess the performance from molecular models of the adsorbent and adsorbates. In this thesis, different computational tool kits are employed to accurately characterise the structural properties of these materials and design a high-throughput protocol that can efficiently screen thousands of materials for membrane-based separations. The results may ultimately help the future design of novel membranes by providing relationships between the best performing materials and their structural design. 2021-08-04 Thesis (University of Nottingham only) NonPeerReviewed application/pdf en arr https://eprints.nottingham.ac.uk/64401/1/JG_revised_thesis.pdf application/pdf en arr https://eprints.nottingham.ac.uk/64401/2/JG_revised_thesis_highlighted.pdf Glover, Joseph (2021) Molecular Simulations of Porous Solids for Adsorption Applications. PhD thesis, University of Nottingham. compuational modelling porous solids adsorption
spellingShingle compuational modelling
porous solids
adsorption
Glover, Joseph
Molecular Simulations of Porous Solids for Adsorption Applications
title Molecular Simulations of Porous Solids for Adsorption Applications
title_full Molecular Simulations of Porous Solids for Adsorption Applications
title_fullStr Molecular Simulations of Porous Solids for Adsorption Applications
title_full_unstemmed Molecular Simulations of Porous Solids for Adsorption Applications
title_short Molecular Simulations of Porous Solids for Adsorption Applications
title_sort molecular simulations of porous solids for adsorption applications
topic compuational modelling
porous solids
adsorption
url https://eprints.nottingham.ac.uk/64401/