Structure and dynamics of iron pentacarbonyl

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Structure and dynamics of iron pentacarbonyl

The dynamics of CO ligand scrambling in Fe(CO)5 has been investigated by linear infrared spectroscopy in supercritical xenon solution. The activation barrier for the Berry pseudorotation in Fe(CO)5 was determined experimentally to be Ea = 2.5 ± 0.4 kcal mol–1 by quantitative analysis of the temperat...

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Bibliographic Details
Main Authors:	Portius, Peter, Bühl, Michael, George, Michael W., Grevels, Friedrich-Wilhelm, Turner, James J.
Format:	Article
Language:	English
Published:	2020
Subjects:	Group theory; Plant derived food; Oscillation; Chemical structure; Infrared light
Online Access:	https://eprints.nottingham.ac.uk/61358/

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