Harnessing metabolic engineering for the production of terpenoids in cyanobacteria

Cyanobacteria are photosynthetic microorganisms that can be engineered to convert carbon dioxide into a myriad of useful chemicals. Terpenoids are the largest class of natural products and have applications in a wide variety of industries including fuels, pharmaceuticals, materials, cosmetics, and f...

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Main Author: Herold, Ryan A.
Format: Thesis (University of Nottingham only)
Language:English
Published: 2020
Subjects:
Online Access:https://eprints.nottingham.ac.uk/60920/
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author Herold, Ryan A.
author_facet Herold, Ryan A.
author_sort Herold, Ryan A.
building Nottingham Research Data Repository
collection Online Access
description Cyanobacteria are photosynthetic microorganisms that can be engineered to convert carbon dioxide into a myriad of useful chemicals. Terpenoids are the largest class of natural products and have applications in a wide variety of industries including fuels, pharmaceuticals, materials, cosmetics, and flavors and fragrances. Many of these compounds can be chemically synthesized or extracted from plants, however this is often either unsustainable or economically prohibitive. An alternative method of production relies on the heterologous expression of terpene synthase enzymes in cyanobacteria, producing the desired terpenoids directly from carbon dioxide. That strategy was explored in this work, whereby a heterologous mevalonate pathway, an enhanced methylerythritol phosphate (MEP) pathway, and a heterologous artemisinin biosynthetic pathway were all designed for expression in both Synechocystis and Synechococcus. Additionally, a heterologous patchoulol synthase from Pogostemon cablin (patchouli) was expressed in a cyanobacterium for the first time. A highly sensitive GC-MS quantification method was developed for the detection of patchoulol, and patchoulol production was characterized under four different growth conditions.
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spelling nottingham-609202025-02-28T12:21:20Z https://eprints.nottingham.ac.uk/60920/ Harnessing metabolic engineering for the production of terpenoids in cyanobacteria Herold, Ryan A. Cyanobacteria are photosynthetic microorganisms that can be engineered to convert carbon dioxide into a myriad of useful chemicals. Terpenoids are the largest class of natural products and have applications in a wide variety of industries including fuels, pharmaceuticals, materials, cosmetics, and flavors and fragrances. Many of these compounds can be chemically synthesized or extracted from plants, however this is often either unsustainable or economically prohibitive. An alternative method of production relies on the heterologous expression of terpene synthase enzymes in cyanobacteria, producing the desired terpenoids directly from carbon dioxide. That strategy was explored in this work, whereby a heterologous mevalonate pathway, an enhanced methylerythritol phosphate (MEP) pathway, and a heterologous artemisinin biosynthetic pathway were all designed for expression in both Synechocystis and Synechococcus. Additionally, a heterologous patchoulol synthase from Pogostemon cablin (patchouli) was expressed in a cyanobacterium for the first time. A highly sensitive GC-MS quantification method was developed for the detection of patchoulol, and patchoulol production was characterized under four different growth conditions. 2020-07-24 Thesis (University of Nottingham only) NonPeerReviewed application/pdf en arr https://eprints.nottingham.ac.uk/60920/1/Herold%20MRes%20Thesis%20Revised%20Final.pdf Herold, Ryan A. (2020) Harnessing metabolic engineering for the production of terpenoids in cyanobacteria. MRes thesis, University of Nottingham. Synthetic biology Metabolic engineering Cyanobacteria Synechocystis sp. PCC 6803 Terpenoid Patchoulol
spellingShingle Synthetic biology
Metabolic engineering
Cyanobacteria
Synechocystis sp. PCC 6803
Terpenoid
Patchoulol
Herold, Ryan A.
Harnessing metabolic engineering for the production of terpenoids in cyanobacteria
title Harnessing metabolic engineering for the production of terpenoids in cyanobacteria
title_full Harnessing metabolic engineering for the production of terpenoids in cyanobacteria
title_fullStr Harnessing metabolic engineering for the production of terpenoids in cyanobacteria
title_full_unstemmed Harnessing metabolic engineering for the production of terpenoids in cyanobacteria
title_short Harnessing metabolic engineering for the production of terpenoids in cyanobacteria
title_sort harnessing metabolic engineering for the production of terpenoids in cyanobacteria
topic Synthetic biology
Metabolic engineering
Cyanobacteria
Synechocystis sp. PCC 6803
Terpenoid
Patchoulol
url https://eprints.nottingham.ac.uk/60920/