N/P-based Sterically Demanding Ligands: Synthesis, Reactivity and Catalysis
This thesis details aims at forming low-coordinate metal complexes, stabilised by N-based ligands, with significant focus on carbazole based systems. The sysnthesis of ligands containing these moieties is first targeted, giving a detailed explanation of how differing synthetic pathways that allow mo...
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| Format: | Thesis (University of Nottingham only) |
| Language: | English |
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2019
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| Online Access: | https://eprints.nottingham.ac.uk/56541/ |
| _version_ | 1848799343437414400 |
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| author | Nolla Saltiel, Roberto |
| author_facet | Nolla Saltiel, Roberto |
| author_sort | Nolla Saltiel, Roberto |
| building | Nottingham Research Data Repository |
| collection | Online Access |
| description | This thesis details aims at forming low-coordinate metal complexes, stabilised by N-based ligands, with significant focus on carbazole based systems. The sysnthesis of ligands containing these moieties is first targeted, giving a detailed explanation of how differing synthetic pathways that allow modifications to the central carbazole core, in turn allow the formation of stable low-coordinate metal centres. Stabilised metal centres derived from these studies, have been found useful in the dehydrogenation of dimethylamine-borane adducts. While also suitable in the selective anti-Markovnikov hydrophosphination of activated alkenes. |
| first_indexed | 2025-11-14T20:34:09Z |
| format | Thesis (University of Nottingham only) |
| id | nottingham-56541 |
| institution | University of Nottingham Malaysia Campus |
| institution_category | Local University |
| language | English |
| last_indexed | 2025-11-14T20:34:09Z |
| publishDate | 2019 |
| recordtype | eprints |
| repository_type | Digital Repository |
| spelling | nottingham-565412025-02-28T14:29:28Z https://eprints.nottingham.ac.uk/56541/ N/P-based Sterically Demanding Ligands: Synthesis, Reactivity and Catalysis Nolla Saltiel, Roberto This thesis details aims at forming low-coordinate metal complexes, stabilised by N-based ligands, with significant focus on carbazole based systems. The sysnthesis of ligands containing these moieties is first targeted, giving a detailed explanation of how differing synthetic pathways that allow modifications to the central carbazole core, in turn allow the formation of stable low-coordinate metal centres. Stabilised metal centres derived from these studies, have been found useful in the dehydrogenation of dimethylamine-borane adducts. While also suitable in the selective anti-Markovnikov hydrophosphination of activated alkenes. 2019-07-17 Thesis (University of Nottingham only) NonPeerReviewed application/pdf en arr https://eprints.nottingham.ac.uk/56541/1/PhD%20Thesis%20Roberto%20Nolla%20Saltiel.pdf Nolla Saltiel, Roberto (2019) N/P-based Sterically Demanding Ligands: Synthesis, Reactivity and Catalysis. PhD thesis, University of Nottingham. ligands carbazoles alkali metal complexes |
| spellingShingle | ligands carbazoles alkali metal complexes Nolla Saltiel, Roberto N/P-based Sterically Demanding Ligands: Synthesis, Reactivity and Catalysis |
| title | N/P-based Sterically Demanding Ligands: Synthesis, Reactivity and Catalysis |
| title_full | N/P-based Sterically Demanding Ligands: Synthesis, Reactivity and Catalysis |
| title_fullStr | N/P-based Sterically Demanding Ligands: Synthesis, Reactivity and Catalysis |
| title_full_unstemmed | N/P-based Sterically Demanding Ligands: Synthesis, Reactivity and Catalysis |
| title_short | N/P-based Sterically Demanding Ligands: Synthesis, Reactivity and Catalysis |
| title_sort | n/p-based sterically demanding ligands: synthesis, reactivity and catalysis |
| topic | ligands carbazoles alkali metal complexes |
| url | https://eprints.nottingham.ac.uk/56541/ |