Rhodium-catalysed arylative cyclisations of malonate esters by 1,4-rhodium migration

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Rhodium-catalysed arylative cyclisations of malonate esters by 1,4-rhodium migration

Rhodium-catalysed intramolecular arylative cyclisations of malonate esters, generating highly functionalised bicycles has been described. The key step is a known alkenyl-to-aryl 1,4-rhodium migration. The reaction is considered to proceed through regioselective carbometallation of the tethered alkyn...

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Bibliographic Details
Main Author:	O'Brien, Luke
Format:	Thesis (University of Nottingham only)
Language:	English
Published:	2019
Subjects:	malonate esters; alkynes; intramolecular arylative cyclisations
Online Access:	https://eprints.nottingham.ac.uk/55998/

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