Synthesis of polydimethylsiloxane microspheres using microfluidics for treatment of Toluene in Wastewater

Monodispersed polydimethylsiloxane (PDMS) microspheres are fabricated by a needle-based versatile microfluidic device with flow-focusing geometry. Microdroplets with various diameters are generated by tuning the flow rate of the dispersed and continuous phase, using single emulsion as the template....

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Main Authors: Lian, Zheng, Ren, Yong, He, Jun, Chen, George Z., Koh, Kai Seng
Format: Book Section
Language:English
Published: ASME 2018
Subjects:
Online Access:https://eprints.nottingham.ac.uk/55924/
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author Lian, Zheng
Ren, Yong
He, Jun
Chen, George Z.
Koh, Kai Seng
author_facet Lian, Zheng
Ren, Yong
He, Jun
Chen, George Z.
Koh, Kai Seng
author_sort Lian, Zheng
building Nottingham Research Data Repository
collection Online Access
description Monodispersed polydimethylsiloxane (PDMS) microspheres are fabricated by a needle-based versatile microfluidic device with flow-focusing geometry. Microdroplets with various diameters are generated by tuning the flow rate of the dispersed and continuous phase, using single emulsion as the template. The collected PDMS microdroplets are then thermally cured to form solid microspheres. We employ an optical microscope to observe the particles and capture photos. The figures are processed by ImageJ which measures the diameter of each particle. The coefficients of variation (CV) of particles are found to be less than 1.5% for all sizes, indicating that a high monodispersity has been achieved. Thereafter, we adopt the PDMS microspheres to a simulated industrial wastewater that contains organic pollutant such as toluene, for removing purposes. Since the solubility parameters of PDMS and toluene are close, toluene molecules can be extracted from its solvent into PDMS. The absorption efficiency provided by PDMS microspheres on organic pollutant such as toluene has been tested by utilizing a Headspace-Gas Chromatography (GC-HS). We then compare the obtained peak signals of toluene before and after treatment to verify the treatment effect. The needle-based microfluidic device is advantageous in its facile assembly and low cost, displaying a great potential for industrial applications.
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language English
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publishDate 2018
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spelling nottingham-559242019-06-10T04:30:15Z https://eprints.nottingham.ac.uk/55924/ Synthesis of polydimethylsiloxane microspheres using microfluidics for treatment of Toluene in Wastewater Lian, Zheng Ren, Yong He, Jun Chen, George Z. Koh, Kai Seng Monodispersed polydimethylsiloxane (PDMS) microspheres are fabricated by a needle-based versatile microfluidic device with flow-focusing geometry. Microdroplets with various diameters are generated by tuning the flow rate of the dispersed and continuous phase, using single emulsion as the template. The collected PDMS microdroplets are then thermally cured to form solid microspheres. We employ an optical microscope to observe the particles and capture photos. The figures are processed by ImageJ which measures the diameter of each particle. The coefficients of variation (CV) of particles are found to be less than 1.5% for all sizes, indicating that a high monodispersity has been achieved. Thereafter, we adopt the PDMS microspheres to a simulated industrial wastewater that contains organic pollutant such as toluene, for removing purposes. Since the solubility parameters of PDMS and toluene are close, toluene molecules can be extracted from its solvent into PDMS. The absorption efficiency provided by PDMS microspheres on organic pollutant such as toluene has been tested by utilizing a Headspace-Gas Chromatography (GC-HS). We then compare the obtained peak signals of toluene before and after treatment to verify the treatment effect. The needle-based microfluidic device is advantageous in its facile assembly and low cost, displaying a great potential for industrial applications. ASME 2018-06-10 Book Section PeerReviewed application/pdf en https://eprints.nottingham.ac.uk/55924/1/2018-PDME%20microspheres%20for%20the%20removal%20of%20toluene-conference%20paper.pdf Lian, Zheng, Ren, Yong, He, Jun, Chen, George Z. and Koh, Kai Seng (2018) Synthesis of polydimethylsiloxane microspheres using microfluidics for treatment of Toluene in Wastewater. In: ASME 2018 16th International Conference on Nanochannels, Microchannels, and Minichannels. ASME, Dubrovnik, V001T12A006. ISBN 9780791851197 Microfluidics ; Sewage http://dx.doi.org/10.1115/ICNMM2018-7775 10.1115/ICNMM2018-7775 10.1115/ICNMM2018-7775 10.1115/ICNMM2018-7775
spellingShingle Microfluidics ; Sewage
Lian, Zheng
Ren, Yong
He, Jun
Chen, George Z.
Koh, Kai Seng
Synthesis of polydimethylsiloxane microspheres using microfluidics for treatment of Toluene in Wastewater
title Synthesis of polydimethylsiloxane microspheres using microfluidics for treatment of Toluene in Wastewater
title_full Synthesis of polydimethylsiloxane microspheres using microfluidics for treatment of Toluene in Wastewater
title_fullStr Synthesis of polydimethylsiloxane microspheres using microfluidics for treatment of Toluene in Wastewater
title_full_unstemmed Synthesis of polydimethylsiloxane microspheres using microfluidics for treatment of Toluene in Wastewater
title_short Synthesis of polydimethylsiloxane microspheres using microfluidics for treatment of Toluene in Wastewater
title_sort synthesis of polydimethylsiloxane microspheres using microfluidics for treatment of toluene in wastewater
topic Microfluidics ; Sewage
url https://eprints.nottingham.ac.uk/55924/
https://eprints.nottingham.ac.uk/55924/
https://eprints.nottingham.ac.uk/55924/