Nickel-catalyzed arylative cyclizations enabled by reversible alkenylnickel E/Z isomerization

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Nickel-catalyzed arylative cyclizations enabled by reversible alkenylnickel E/Z isomerization

Herein is described the first enantioselective intramolecular allylation of alkenylnickel nucleophiles. These reactions are initiated by the addition of an arylboronic acid across an alkyne, followed by cyclization of the resulting alkenylnickel species onto an allylic phosphate. The reversible E/Z...

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Bibliographic Details
Main Author:	Yap, Connor
Format:	Thesis (University of Nottingham only)
Language:	English
Published:	2019
Subjects:	Enantioselective intramolecular allylation; Alkenylnickel nucleophiles
Online Access:	https://eprints.nottingham.ac.uk/55829/

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