Post-functionalization of a photoactive hybrid polyoxotungstate
A new post-functionalization strategy for hybrid polyoxometalate (POM) clusters is presented, whereby the electronic properties and visible-light driven oxidative reactivity of the POM core can be altered by controlled addition of transition metal ions. The structure of three new metal-functionalise...
| Main Authors: | , , , , |
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| Format: | Article |
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Royal Society of Chemistry
2018
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| Online Access: | https://eprints.nottingham.ac.uk/52302/ |
| _version_ | 1848798694664568832 |
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| author | Cameron, Jamie M. Fujimoto, Satomi Wei, Rong-Jia Newton, Graham N. Oshio, Hiroki |
| author_facet | Cameron, Jamie M. Fujimoto, Satomi Wei, Rong-Jia Newton, Graham N. Oshio, Hiroki |
| author_sort | Cameron, Jamie M. |
| building | Nottingham Research Data Repository |
| collection | Online Access |
| description | A new post-functionalization strategy for hybrid polyoxometalate (POM) clusters is presented, whereby the electronic properties and visible-light driven oxidative reactivity of the POM core can be altered by controlled addition of transition metal ions. The structure of three new metal-functionalised derivatives of a phosphonate hybrid-POM are discussed, alongside a comparison of their electrochemical, photo-chemical and photo-oxidative properties. |
| first_indexed | 2025-11-14T20:23:51Z |
| format | Article |
| id | nottingham-52302 |
| institution | University of Nottingham Malaysia Campus |
| institution_category | Local University |
| last_indexed | 2025-11-14T20:23:51Z |
| publishDate | 2018 |
| publisher | Royal Society of Chemistry |
| recordtype | eprints |
| repository_type | Digital Repository |
| spelling | nottingham-523022020-05-04T19:36:37Z https://eprints.nottingham.ac.uk/52302/ Post-functionalization of a photoactive hybrid polyoxotungstate Cameron, Jamie M. Fujimoto, Satomi Wei, Rong-Jia Newton, Graham N. Oshio, Hiroki A new post-functionalization strategy for hybrid polyoxometalate (POM) clusters is presented, whereby the electronic properties and visible-light driven oxidative reactivity of the POM core can be altered by controlled addition of transition metal ions. The structure of three new metal-functionalised derivatives of a phosphonate hybrid-POM are discussed, alongside a comparison of their electrochemical, photo-chemical and photo-oxidative properties. Royal Society of Chemistry 2018-05-15 Article PeerReviewed Cameron, Jamie M., Fujimoto, Satomi, Wei, Rong-Jia, Newton, Graham N. and Oshio, Hiroki (2018) Post-functionalization of a photoactive hybrid polyoxotungstate. Dalton Transactions . ISSN 1477-9234 http://pubs.rsc.org/en/content/articlelanding/2018/dt/c8dt01253a#!divAbstract doi:10.1039/C8DT01253A doi:10.1039/C8DT01253A |
| spellingShingle | Cameron, Jamie M. Fujimoto, Satomi Wei, Rong-Jia Newton, Graham N. Oshio, Hiroki Post-functionalization of a photoactive hybrid polyoxotungstate |
| title | Post-functionalization of a photoactive hybrid polyoxotungstate |
| title_full | Post-functionalization of a photoactive hybrid polyoxotungstate |
| title_fullStr | Post-functionalization of a photoactive hybrid polyoxotungstate |
| title_full_unstemmed | Post-functionalization of a photoactive hybrid polyoxotungstate |
| title_short | Post-functionalization of a photoactive hybrid polyoxotungstate |
| title_sort | post-functionalization of a photoactive hybrid polyoxotungstate |
| url | https://eprints.nottingham.ac.uk/52302/ https://eprints.nottingham.ac.uk/52302/ https://eprints.nottingham.ac.uk/52302/ |