Epitaxial growth of γ-InSe and α, β, and γ-In2Se3 on ε-GaSe

We demonstrate that γ-InSe and the α, β and γ phases of In2Se3 can be grown epitaxially on ε-GaSe substrates using a physical vapour transport method. By exploiting the temperature gradient within the tube furnace, we can grow selectively different phases of InxSey depending on the position of the s...

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Main Authors: Balakrishnan, Nilanthy, Steer, Elisabeth D., Smith, Emily F., Kudrynskyi, Zakhar R., Kovalyuk, Zakhar D., Eaves, Laurence, Patanè, Amalia, Beton, Peter H.
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Published: IOP Publishing 2018
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Online Access:https://eprints.nottingham.ac.uk/51793/
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author Balakrishnan, Nilanthy
Steer, Elisabeth D.
Smith, Emily F.
Kudrynskyi, Zakhar R.
Kovalyuk, Zakhar D.
Eaves, Laurence
Patanè, Amalia
Beton, Peter H.
author_facet Balakrishnan, Nilanthy
Steer, Elisabeth D.
Smith, Emily F.
Kudrynskyi, Zakhar R.
Kovalyuk, Zakhar D.
Eaves, Laurence
Patanè, Amalia
Beton, Peter H.
author_sort Balakrishnan, Nilanthy
building Nottingham Research Data Repository
collection Online Access
description We demonstrate that γ-InSe and the α, β and γ phases of In2Se3 can be grown epitaxially on ε-GaSe substrates using a physical vapour transport method. By exploiting the temperature gradient within the tube furnace, we can grow selectively different phases of InxSey depending on the position of the substrate within the furnace. The uniform cleaved surface of ε-GaSe enables the epitaxial growth of the InxSey layers, which are aligned over large areas. The InxSey epilayers are characterised using Raman, photoluminescence, X-ray photoelectron and electron dispersive X-ray spectroscopies. Each InxSey phase and stoichiometry exhibits distinct optical and vibrational properties, providing a tuneable photoluminescence emission range from 1.3 eV to ~ 2 eV suitable for exploitation in electronics and optoelectronics.
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spelling nottingham-517932020-05-04T19:38:31Z https://eprints.nottingham.ac.uk/51793/ Epitaxial growth of γ-InSe and α, β, and γ-In2Se3 on ε-GaSe Balakrishnan, Nilanthy Steer, Elisabeth D. Smith, Emily F. Kudrynskyi, Zakhar R. Kovalyuk, Zakhar D. Eaves, Laurence Patanè, Amalia Beton, Peter H. We demonstrate that γ-InSe and the α, β and γ phases of In2Se3 can be grown epitaxially on ε-GaSe substrates using a physical vapour transport method. By exploiting the temperature gradient within the tube furnace, we can grow selectively different phases of InxSey depending on the position of the substrate within the furnace. The uniform cleaved surface of ε-GaSe enables the epitaxial growth of the InxSey layers, which are aligned over large areas. The InxSey epilayers are characterised using Raman, photoluminescence, X-ray photoelectron and electron dispersive X-ray spectroscopies. Each InxSey phase and stoichiometry exhibits distinct optical and vibrational properties, providing a tuneable photoluminescence emission range from 1.3 eV to ~ 2 eV suitable for exploitation in electronics and optoelectronics. IOP Publishing 2018-06-01 Article PeerReviewed Balakrishnan, Nilanthy, Steer, Elisabeth D., Smith, Emily F., Kudrynskyi, Zakhar R., Kovalyuk, Zakhar D., Eaves, Laurence, Patanè, Amalia and Beton, Peter H. (2018) Epitaxial growth of γ-InSe and α, β, and γ-In2Se3 on ε-GaSe. 2D Materials, 5 (3). 035026. ISSN 2053-1583 Indium Selenide III-VI van der Waals layered crystals 2D materials physical vapour transport http://iopscience.iop.org/article/10.1088/2053-1583/aac479 doi:10.1088/2053-1583/aac479 doi:10.1088/2053-1583/aac479
spellingShingle Indium Selenide
III-VI van der Waals layered crystals
2D materials
physical vapour transport
Balakrishnan, Nilanthy
Steer, Elisabeth D.
Smith, Emily F.
Kudrynskyi, Zakhar R.
Kovalyuk, Zakhar D.
Eaves, Laurence
Patanè, Amalia
Beton, Peter H.
Epitaxial growth of γ-InSe and α, β, and γ-In2Se3 on ε-GaSe
title Epitaxial growth of γ-InSe and α, β, and γ-In2Se3 on ε-GaSe
title_full Epitaxial growth of γ-InSe and α, β, and γ-In2Se3 on ε-GaSe
title_fullStr Epitaxial growth of γ-InSe and α, β, and γ-In2Se3 on ε-GaSe
title_full_unstemmed Epitaxial growth of γ-InSe and α, β, and γ-In2Se3 on ε-GaSe
title_short Epitaxial growth of γ-InSe and α, β, and γ-In2Se3 on ε-GaSe
title_sort epitaxial growth of γ-inse and α, β, and γ-in2se3 on ε-gase
topic Indium Selenide
III-VI van der Waals layered crystals
2D materials
physical vapour transport
url https://eprints.nottingham.ac.uk/51793/
https://eprints.nottingham.ac.uk/51793/
https://eprints.nottingham.ac.uk/51793/