Switchable synthesis of Z-homoallylic boronates and E-allylic
boronates by enantioselective copper-catalyzed 1,6-boration
The enantioselective Cu-catalyzed 1,6-boration of (E,E) α,β,γ,δ-unsaturated ketones is described, which gives homoallylic boronates with high enantiomeric purity and unexpectedly high Zselectivity. By changing the solvent, the outcome can be altered to give E-allylic boronates.
Bibliographic Details
| Main Authors: |
Luo, Yunfei,
Wales, Steven M.,
Korkis, Stamatis E.,
Roy, Iain D.,
Lewis, William,
Lam, Hon Wai |
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| Format: | Article
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| Published: |
Wiley
2018
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| Subjects: | |
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| Online Access: | https://eprints.nottingham.ac.uk/51268/
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