Flexible and transparent films produced from cellulose nanowhisker reinforced agarose

Transparent and flexible nanocomposite films with a range of Agarose to Cellulose Nano-Whisker (CNW) ratios were produced using never-dried CNWs. The incorporation of never-dried CNWs within Agarose played an important role in the surface roughness (Ra 7–15 nm) and light transparency of the films (f...

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Main Authors: Felfel, Reda M., Hossain, Kazi M. Zakir, Kabir, Sumaya F., Yee, Soon L., Ahmed, Ifty, Grant, David M.
Format: Article
Published: Elsevier 2018
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Online Access:https://eprints.nottingham.ac.uk/51162/
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author Felfel, Reda M.
Hossain, Kazi M. Zakir
Kabir, Sumaya F.
Yee, Soon L.
Ahmed, Ifty
Grant, David M.
author_facet Felfel, Reda M.
Hossain, Kazi M. Zakir
Kabir, Sumaya F.
Yee, Soon L.
Ahmed, Ifty
Grant, David M.
author_sort Felfel, Reda M.
building Nottingham Research Data Repository
collection Online Access
description Transparent and flexible nanocomposite films with a range of Agarose to Cellulose Nano-Whisker (CNW) ratios were produced using never-dried CNWs. The incorporation of never-dried CNWs within Agarose played an important role in the surface roughness (Ra 7–15 nm) and light transparency of the films (from 84 to 90%). Surface induced crystallisation of Agarose by CNWs was also found with increasing percentage of crystallinity (up to 79%) for the nanocomposite films, where CNW acted as nucleating sites. The enhanced tensile strength (ca. 30% increase) and modulus (ca. 90% increase) properties of the nanocomposite films compared to the control Agarose film indicated the effectiveness of the nanowhiskers incorporation. The storage modulus of the nanocomposite films increased also to be tripled Agarose alone as the CNWs content reached 43%. The swelling kinetics of the nanocomposites revealed that addition of CNWs reduced the long-term swelling capacity and swelling rate of the nanocomposite.
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spelling nottingham-511622020-05-04T19:48:28Z https://eprints.nottingham.ac.uk/51162/ Flexible and transparent films produced from cellulose nanowhisker reinforced agarose Felfel, Reda M. Hossain, Kazi M. Zakir Kabir, Sumaya F. Yee, Soon L. Ahmed, Ifty Grant, David M. Transparent and flexible nanocomposite films with a range of Agarose to Cellulose Nano-Whisker (CNW) ratios were produced using never-dried CNWs. The incorporation of never-dried CNWs within Agarose played an important role in the surface roughness (Ra 7–15 nm) and light transparency of the films (from 84 to 90%). Surface induced crystallisation of Agarose by CNWs was also found with increasing percentage of crystallinity (up to 79%) for the nanocomposite films, where CNW acted as nucleating sites. The enhanced tensile strength (ca. 30% increase) and modulus (ca. 90% increase) properties of the nanocomposite films compared to the control Agarose film indicated the effectiveness of the nanowhiskers incorporation. The storage modulus of the nanocomposite films increased also to be tripled Agarose alone as the CNWs content reached 43%. The swelling kinetics of the nanocomposites revealed that addition of CNWs reduced the long-term swelling capacity and swelling rate of the nanocomposite. Elsevier 2018-08-15 Article PeerReviewed Felfel, Reda M., Hossain, Kazi M. Zakir, Kabir, Sumaya F., Yee, Soon L., Ahmed, Ifty and Grant, David M. (2018) Flexible and transparent films produced from cellulose nanowhisker reinforced agarose. Carbohydrate Polymers, 194 . pp. 328-338. ISSN 1879-1344 Cellulose nanowhiskers; Agarose; Transparency; Crystallinity; Tensile properties; Swelling kinetics https://www.sciencedirect.com/science/article/pii/S0144861718303734 doi:10.1016/j.carbpol.2018.04.005 doi:10.1016/j.carbpol.2018.04.005
spellingShingle Cellulose nanowhiskers; Agarose; Transparency; Crystallinity; Tensile properties; Swelling kinetics
Felfel, Reda M.
Hossain, Kazi M. Zakir
Kabir, Sumaya F.
Yee, Soon L.
Ahmed, Ifty
Grant, David M.
Flexible and transparent films produced from cellulose nanowhisker reinforced agarose
title Flexible and transparent films produced from cellulose nanowhisker reinforced agarose
title_full Flexible and transparent films produced from cellulose nanowhisker reinforced agarose
title_fullStr Flexible and transparent films produced from cellulose nanowhisker reinforced agarose
title_full_unstemmed Flexible and transparent films produced from cellulose nanowhisker reinforced agarose
title_short Flexible and transparent films produced from cellulose nanowhisker reinforced agarose
title_sort flexible and transparent films produced from cellulose nanowhisker reinforced agarose
topic Cellulose nanowhiskers; Agarose; Transparency; Crystallinity; Tensile properties; Swelling kinetics
url https://eprints.nottingham.ac.uk/51162/
https://eprints.nottingham.ac.uk/51162/
https://eprints.nottingham.ac.uk/51162/