Influence of KCl and HCl on high temperature corrosion of HVAF-sprayed NiCrAlY and NiCrMo coatings

The oxidation performance of NiCrAlY and NiCrMo coatings thermally sprayed by high velocity air-fuel (HVAF) technique has been investigated in a chloridizing-oxidizing environment, with and without a KCl deposit, at 600 °C for up to 168 h. Both coatings protected the substrate in the absence of KCl...

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Main Authors: Sadeghimeresht, Esmaeil, Reddy, Liam, Hussain, Tanvir, Huhtakangas, Matti, Markocsan, Nicolaie, Joshi, Shrikant
Format: Article
Published: Elsevier 2018
Subjects:
Online Access:https://eprints.nottingham.ac.uk/51038/
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author Sadeghimeresht, Esmaeil
Reddy, Liam
Hussain, Tanvir
Huhtakangas, Matti
Markocsan, Nicolaie
Joshi, Shrikant
author_facet Sadeghimeresht, Esmaeil
Reddy, Liam
Hussain, Tanvir
Huhtakangas, Matti
Markocsan, Nicolaie
Joshi, Shrikant
author_sort Sadeghimeresht, Esmaeil
building Nottingham Research Data Repository
collection Online Access
description The oxidation performance of NiCrAlY and NiCrMo coatings thermally sprayed by high velocity air-fuel (HVAF) technique has been investigated in a chloridizing-oxidizing environment, with and without a KCl deposit, at 600 °C for up to 168 h. Both coatings protected the substrate in the absence of KCl due to formation of a dense Cr-rich oxide scale. In the presence of KCl, Cl−/Cl2 diffused through a non-protective and porous NiCr2O4 scale formed on NiCrAlY, leading to formation of volatile CrCl3. On the other hand, Mo in NiCrMo stimulated the formation of a more protective Cr-rich oxide scale which increased the corrosion resistance by reducing Cl−/Cl2 diffusion.
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spelling nottingham-510382020-05-04T19:40:56Z https://eprints.nottingham.ac.uk/51038/ Influence of KCl and HCl on high temperature corrosion of HVAF-sprayed NiCrAlY and NiCrMo coatings Sadeghimeresht, Esmaeil Reddy, Liam Hussain, Tanvir Huhtakangas, Matti Markocsan, Nicolaie Joshi, Shrikant The oxidation performance of NiCrAlY and NiCrMo coatings thermally sprayed by high velocity air-fuel (HVAF) technique has been investigated in a chloridizing-oxidizing environment, with and without a KCl deposit, at 600 °C for up to 168 h. Both coatings protected the substrate in the absence of KCl due to formation of a dense Cr-rich oxide scale. In the presence of KCl, Cl−/Cl2 diffused through a non-protective and porous NiCr2O4 scale formed on NiCrAlY, leading to formation of volatile CrCl3. On the other hand, Mo in NiCrMo stimulated the formation of a more protective Cr-rich oxide scale which increased the corrosion resistance by reducing Cl−/Cl2 diffusion. Elsevier 2018-06-15 Article PeerReviewed Sadeghimeresht, Esmaeil, Reddy, Liam, Hussain, Tanvir, Huhtakangas, Matti, Markocsan, Nicolaie and Joshi, Shrikant (2018) Influence of KCl and HCl on high temperature corrosion of HVAF-sprayed NiCrAlY and NiCrMo coatings. Materials & Design, 148 . pp. 17-29. ISSN 0264-1275 Thermal spray coating; NiCrAlYNiCrMo; High-velocity air fuel (HVAF); Biomass-/waste-fired boiler; Fireside corrosion https://www.sciencedirect.com/science/article/pii/S0264127518302338 doi:10.1016/j.matdes.2018.03.048 doi:10.1016/j.matdes.2018.03.048
spellingShingle Thermal spray coating; NiCrAlYNiCrMo; High-velocity air fuel (HVAF); Biomass-/waste-fired boiler; Fireside corrosion
Sadeghimeresht, Esmaeil
Reddy, Liam
Hussain, Tanvir
Huhtakangas, Matti
Markocsan, Nicolaie
Joshi, Shrikant
Influence of KCl and HCl on high temperature corrosion of HVAF-sprayed NiCrAlY and NiCrMo coatings
title Influence of KCl and HCl on high temperature corrosion of HVAF-sprayed NiCrAlY and NiCrMo coatings
title_full Influence of KCl and HCl on high temperature corrosion of HVAF-sprayed NiCrAlY and NiCrMo coatings
title_fullStr Influence of KCl and HCl on high temperature corrosion of HVAF-sprayed NiCrAlY and NiCrMo coatings
title_full_unstemmed Influence of KCl and HCl on high temperature corrosion of HVAF-sprayed NiCrAlY and NiCrMo coatings
title_short Influence of KCl and HCl on high temperature corrosion of HVAF-sprayed NiCrAlY and NiCrMo coatings
title_sort influence of kcl and hcl on high temperature corrosion of hvaf-sprayed nicraly and nicrmo coatings
topic Thermal spray coating; NiCrAlYNiCrMo; High-velocity air fuel (HVAF); Biomass-/waste-fired boiler; Fireside corrosion
url https://eprints.nottingham.ac.uk/51038/
https://eprints.nottingham.ac.uk/51038/
https://eprints.nottingham.ac.uk/51038/