Synthesis and thermoelectric properties of 2- and 2,8-substituted tetrathiotetracenes

Synthesis and thermoelectric properties of 2- and 2,8-substituted tetrathiotetracenes

Reaction of elemental sulfur with 2-R1 and 2,8-R1,R2-substituted tetracenes (2) in refluxing DMF affords 5,6,11,12 tetrathiotetracenes (1) in good yields (74-99%) for a range of substituents where R1,R2 are: H,H (a); Me,H (b); MeO,H (c); Ph,H (d); Me,Me (e), iPr,Me (f, iPr = iso-propyl, CHMe2), Me,M...

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Main Authors: Robert Garrett, Mary, Durán-Peña, María Jesús, Lewis, Willliam, Pudzs, Kaspars, Uzulis, Janis, Mihailovs, Igors, Tyril, Björk, Shine, Jonathan, Smith, Emily F., Rutkis, Martins, Woodward, Simon
Format: Article
Language:English
Published: Royal Society of Chemistry 2018
Online Access:https://eprints.nottingham.ac.uk/50403/

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