One-carbon oxidative annulations of 1,3-enynes by catalytic C–H functionalization and 1,4-rhodium(III) migration

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One-carbon oxidative annulations of 1,3-enynes by catalytic C–H functionalization and 1,4-rhodium(III) migration

Rhodium(III)-catalyzed C-H functionalization-oxidative annulations of aromatic substrates with 1,3-enynes that contain allylic hydrogen atoms cis to the alkyne are described. The key step in these reactions is an alkenyl-to-allyl 1,4-rhodium(III) migration to give electrophilic pi-allylrhodium(III)...

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Bibliographic Details
Main Authors:	Dooley, Johnathon D., Lam, Hon Wai
Format:	Article
Language:	English
Published:	Wiley 2018
Subjects:	catalysis; C-H functionalization; enyne; Isomerization; rhodium
Online Access:	https://eprints.nottingham.ac.uk/49295/

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