Dehydrocoupling of dimethylamine-borane promoted by manganese(II) m-terphenyl complexes

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Dehydrocoupling of dimethylamine-borane promoted by manganese(II) m-terphenyl complexes

Two- and three-coordinate manganese m-terphenyl complexes are precatalysts for the dehydrogenation of dimethylamine-borane (Me2NH·BH3) affording one equivalent of molecular hydrogen and half an equivalent of [Me2N–BH2]2. Experimental studies into the nature of the catalyst indicate that small change...

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Bibliographic Details
Main Authors:	Sharpe, Helen R., Geer, Ana M., Blundell, Toby J., Hastings, Fiona R., Fay, Michael W., Rance, Graham A., Lewis, William, Blake, Alexander J., Kays, Deborah L.
Format:	Article
Published:	Royal Society of Chemistry 2017
Online Access:	https://eprints.nottingham.ac.uk/48950/

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