New reactive sites enabled via an allyl-to-allyl 1,4-Rh(III) migration

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New reactive sites enabled via an allyl-to-allyl 1,4-Rh(III) migration

The Rh(III)-catalysed oxidative C–H allylation and homoallylation of N-acetylbenzamides with 1,3-dienes is described. The presence of allylic hydrogens cis to the less substituted alkene of the 1,3-diene is important for the success of these reactions, though not essential. With the assistance of re...

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Bibliographic Details
Main Author:	Korkis, Stamatis E.
Format:	Thesis (University of Nottingham only)
Language:	English
Published:	2018
Subjects:	Rh(III)-catalysis directed and remote C-H functionalisation 1 4-migration 4-allylic transposition chain-walking allylic isomerisation β-hydride elimination
Online Access:	https://eprints.nottingham.ac.uk/48787/

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