An on-surface reaction confined within a porous molecular template
On-surface reactions based on metal-catalysed Ullmann coupling have been successfully employed to synthesise a wide variety of covalently coupled structures. Substrate chemistry and topology are both known to effect the progression of an on-surface reaction; offering routes to control efficiency and...
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| Format: | Article |
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Wiley-VCH Verlag
2018
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| Online Access: | https://eprints.nottingham.ac.uk/47579/ |
| _version_ | 1848797581110411264 |
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| author | Judd, Chris J. Champness, Neil R. Saywell, Alexander |
| author_facet | Judd, Chris J. Champness, Neil R. Saywell, Alexander |
| author_sort | Judd, Chris J. |
| building | Nottingham Research Data Repository |
| collection | Online Access |
| description | On-surface reactions based on metal-catalysed Ullmann coupling have been successfully employed to synthesise a wide variety of covalently coupled structures. Substrate chemistry and topology are both known to effect the progression of an on-surface reaction; offering routes to control efficiency and selectivity. Here, we detail ultra-high vacuum scanning probe microscopy experiments showing that templating a catalytically active surface, via a supramolecular template, influences the reaction pathway of an onsurface Ullmann-type coupling reaction by inhibiting one potential intermediate structure and stabilising another. |
| first_indexed | 2025-11-14T20:06:09Z |
| format | Article |
| id | nottingham-47579 |
| institution | University of Nottingham Malaysia Campus |
| institution_category | Local University |
| last_indexed | 2025-11-14T20:06:09Z |
| publishDate | 2018 |
| publisher | Wiley-VCH Verlag |
| recordtype | eprints |
| repository_type | Digital Repository |
| spelling | nottingham-475792020-05-04T19:25:19Z https://eprints.nottingham.ac.uk/47579/ An on-surface reaction confined within a porous molecular template Judd, Chris J. Champness, Neil R. Saywell, Alexander On-surface reactions based on metal-catalysed Ullmann coupling have been successfully employed to synthesise a wide variety of covalently coupled structures. Substrate chemistry and topology are both known to effect the progression of an on-surface reaction; offering routes to control efficiency and selectivity. Here, we detail ultra-high vacuum scanning probe microscopy experiments showing that templating a catalytically active surface, via a supramolecular template, influences the reaction pathway of an onsurface Ullmann-type coupling reaction by inhibiting one potential intermediate structure and stabilising another. Wiley-VCH Verlag 2018-01-02 Article PeerReviewed Judd, Chris J., Champness, Neil R. and Saywell, Alexander (2018) An on-surface reaction confined within a porous molecular template. Chemistry - a European Journal, 24 (1). pp. 56-61. ISSN 1521-3765 heterogeneous catalysis; supramolecular chemistry; scanning probe microscopy; surface chemistry; templated reactions http://onlinelibrary.wiley.com/doi/10.1002/chem.201704693/abstract doi:10.1002/chem.201704693 doi:10.1002/chem.201704693 |
| spellingShingle | heterogeneous catalysis; supramolecular chemistry; scanning probe microscopy; surface chemistry; templated reactions Judd, Chris J. Champness, Neil R. Saywell, Alexander An on-surface reaction confined within a porous molecular template |
| title | An on-surface reaction confined within a porous molecular
template |
| title_full | An on-surface reaction confined within a porous molecular
template |
| title_fullStr | An on-surface reaction confined within a porous molecular
template |
| title_full_unstemmed | An on-surface reaction confined within a porous molecular
template |
| title_short | An on-surface reaction confined within a porous molecular
template |
| title_sort | on-surface reaction confined within a porous molecular
template |
| topic | heterogeneous catalysis; supramolecular chemistry; scanning probe microscopy; surface chemistry; templated reactions |
| url | https://eprints.nottingham.ac.uk/47579/ https://eprints.nottingham.ac.uk/47579/ https://eprints.nottingham.ac.uk/47579/ |