Thermal and photochemical mechanisms for cyclobutane formation in bielschowskysin biosynthesis

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Thermal and photochemical mechanisms for cyclobutane formation in bielschowskysin biosynthesis

The unique structure of furanocembranoid natural product bielschowskysin has provoked a number of biosynthetic hypotheses: quantum chemical calculations provide a means to assess the feasibility of postulated mechanisms in the construction of this unusual carbon skeleton. Calculations reveal that th...

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Bibliographic Details
Main Authors:	Tang, Bencan, Simion, Robert, Paton, Robert S.
Format:	Article
Published:	Thieme 2015
Subjects:	biosynthesis; concerted; cyclization; DFT; transition states
Online Access:	https://eprints.nottingham.ac.uk/47353/

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