Enantioselective rhodium-catalyzed coupling of arylboronic acids, 1,3-enynes, and Imines by alkenyl-to-allyl 1,4-rhodium(I) migration

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Enantioselective rhodium-catalyzed coupling of arylboronic acids, 1,3-enynes, and Imines by alkenyl-to-allyl 1,4-rhodium(I) migration

A chiral rhodium complex catalyzes the highly enantioselective coupling of arylboronic acids, 1,3-enynes, and imines to give homoallylic sulfamates. The key step is the generation of allylrhodium(I) species by alkenyl-to-allyl 1,4-rhodium(I) migration.

Bibliographic Details
Main Authors:	Callingham, Michael, Partridge, Benjamin M., Lewis, William, Lam, Hon Wai
Format:	Article
Published:	Wiley-VCH Verlag 2017
Subjects:	arylboronic acid; 1 4-migration; imine
Online Access:	https://eprints.nottingham.ac.uk/47300/

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