Enantioselective rhodium-catalyzed coupling of arylboronic acids, 1,3-enynes, and Imines by alkenyl-to-allyl 1,4-rhodium(I) migration
A chiral rhodium complex catalyzes the highly enantioselective coupling of arylboronic acids, 1,3-enynes, and imines to give homoallylic sulfamates. The key step is the generation of allylrhodium(I) species by alkenyl-to-allyl 1,4-rhodium(I) migration.
| Main Authors: | , , , |
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| Format: | Article |
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Wiley-VCH Verlag
2017
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| Online Access: | https://eprints.nottingham.ac.uk/47300/ |
| _version_ | 1848797510975356928 |
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| author | Callingham, Michael Partridge, Benjamin M. Lewis, William Lam, Hon Wai |
| author_facet | Callingham, Michael Partridge, Benjamin M. Lewis, William Lam, Hon Wai |
| author_sort | Callingham, Michael |
| building | Nottingham Research Data Repository |
| collection | Online Access |
| description | A chiral rhodium complex catalyzes the highly enantioselective coupling of arylboronic acids, 1,3-enynes, and imines to give homoallylic sulfamates. The key step is the generation of allylrhodium(I) species by alkenyl-to-allyl 1,4-rhodium(I) migration. |
| first_indexed | 2025-11-14T20:05:02Z |
| format | Article |
| id | nottingham-47300 |
| institution | University of Nottingham Malaysia Campus |
| institution_category | Local University |
| last_indexed | 2025-11-14T20:05:02Z |
| publishDate | 2017 |
| publisher | Wiley-VCH Verlag |
| recordtype | eprints |
| repository_type | Digital Repository |
| spelling | nottingham-473002020-05-04T19:22:53Z https://eprints.nottingham.ac.uk/47300/ Enantioselective rhodium-catalyzed coupling of arylboronic acids, 1,3-enynes, and Imines by alkenyl-to-allyl 1,4-rhodium(I) migration Callingham, Michael Partridge, Benjamin M. Lewis, William Lam, Hon Wai A chiral rhodium complex catalyzes the highly enantioselective coupling of arylboronic acids, 1,3-enynes, and imines to give homoallylic sulfamates. The key step is the generation of allylrhodium(I) species by alkenyl-to-allyl 1,4-rhodium(I) migration. Wiley-VCH Verlag 2017-12-18 Article PeerReviewed Callingham, Michael, Partridge, Benjamin M., Lewis, William and Lam, Hon Wai (2017) Enantioselective rhodium-catalyzed coupling of arylboronic acids, 1,3-enynes, and Imines by alkenyl-to-allyl 1,4-rhodium(I) migration. Angewandte Chemie International Edition, 56 (51). pp. 16352-16356. ISSN 1521-3773 arylboronic acid; 1 4-migration; imine http://onlinelibrary.wiley.com/doi/10.1002/anie.201709334/abstract doi:10.1002/anie.201709334 doi:10.1002/anie.201709334 |
| spellingShingle | arylboronic acid; 1 4-migration; imine Callingham, Michael Partridge, Benjamin M. Lewis, William Lam, Hon Wai Enantioselective rhodium-catalyzed coupling of arylboronic acids, 1,3-enynes, and Imines by alkenyl-to-allyl 1,4-rhodium(I) migration |
| title | Enantioselective rhodium-catalyzed coupling of arylboronic acids, 1,3-enynes, and Imines by alkenyl-to-allyl 1,4-rhodium(I) migration |
| title_full | Enantioselective rhodium-catalyzed coupling of arylboronic acids, 1,3-enynes, and Imines by alkenyl-to-allyl 1,4-rhodium(I) migration |
| title_fullStr | Enantioselective rhodium-catalyzed coupling of arylboronic acids, 1,3-enynes, and Imines by alkenyl-to-allyl 1,4-rhodium(I) migration |
| title_full_unstemmed | Enantioselective rhodium-catalyzed coupling of arylboronic acids, 1,3-enynes, and Imines by alkenyl-to-allyl 1,4-rhodium(I) migration |
| title_short | Enantioselective rhodium-catalyzed coupling of arylboronic acids, 1,3-enynes, and Imines by alkenyl-to-allyl 1,4-rhodium(I) migration |
| title_sort | enantioselective rhodium-catalyzed coupling of arylboronic acids, 1,3-enynes, and imines by alkenyl-to-allyl 1,4-rhodium(i) migration |
| topic | arylboronic acid; 1 4-migration; imine |
| url | https://eprints.nottingham.ac.uk/47300/ https://eprints.nottingham.ac.uk/47300/ https://eprints.nottingham.ac.uk/47300/ |