Comparison of rhenium–porphyrin dyads for CO₂ photoreduction: photocatalytic studies and charge separation dynamics studied by time-resolved IR spectroscopy

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Comparison of rhenium–porphyrin dyads for CO₂ photoreduction: photocatalytic studies and charge separation dynamics studied by time-resolved IR spectroscopy

We report a study of the photocatalytic reduction of CO₂ to CO by zinc porphyrins covalently linked to [ReI(2,2′-bipyridine)(CO)₃L]⁺/⁰ moieties with visible light of wavelength >520 nm. Dyad 1 contains an amide C₆H₄NHC(O) link from porphyrin to bipyridine (Bpy), Dyad 2 contains an additional meth...

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Bibliographic Details
Main Authors:	Windle, Christopher D., George, Michael W., Perutz, Robin N., Summers, Peter A., Sun, Xue Zhong, Whitwood, Adrian C.
Format:	Article
Published:	Royal Society of Chemistry 2015
Online Access:	https://eprints.nottingham.ac.uk/47199/

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