Nickel(II) metal-organic frameworks with N,N’-di(4-pyridyl)-1,4,5,8-naphthalenetetracarboxydiimide ligands: influence of secondary building unit geometry on dimensionality and framework dimensions
When Ni(NO3)2∙6H2O and N,N’-di(4-pyridyl)-1,4,5,8-naphthalenetetracarboxydiimide (DPNDI) are reacted, a one-dimensional coordination polymer (1) is formed. However, reaction with either terephthalic acid (2) or 2,6-naphthalenedicarboxylic acid (3) affords two-dimensional, pillared metal-organic fram...
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| Format: | Article |
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Royal Society of Chemistry
2017
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| Online Access: | https://eprints.nottingham.ac.uk/46944/ |
| _version_ | 1848797434111590400 |
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| author | Pfeiffer, Constance R. Biggins, Naomi H. Lewis, William Champness, Neil R. |
| author_facet | Pfeiffer, Constance R. Biggins, Naomi H. Lewis, William Champness, Neil R. |
| author_sort | Pfeiffer, Constance R. |
| building | Nottingham Research Data Repository |
| collection | Online Access |
| description | When Ni(NO3)2∙6H2O and N,N’-di(4-pyridyl)-1,4,5,8-naphthalenetetracarboxydiimide (DPNDI) are reacted, a one-dimensional coordination polymer (1) is formed. However, reaction with either terephthalic acid (2) or 2,6-naphthalenedicarboxylic acid (3) affords two-dimensional, pillared metal-organic frameworks. 2 and 3 containing rectangular voids of different dimensions which are dictated by the carboxylate ligand and the arrangement of the [M(k2-O2NO)]2(μ2-O2CR)2] secondary building unit (SBU) that forms the nodes of the framework. The role of SBU geometry, intermolecular face-to-face π–π and lone pair–π interactions involving the DPNDI ligands are discussed. |
| first_indexed | 2025-11-14T20:03:49Z |
| format | Article |
| id | nottingham-46944 |
| institution | University of Nottingham Malaysia Campus |
| institution_category | Local University |
| last_indexed | 2025-11-14T20:03:49Z |
| publishDate | 2017 |
| publisher | Royal Society of Chemistry |
| recordtype | eprints |
| repository_type | Digital Repository |
| spelling | nottingham-469442020-05-04T19:04:36Z https://eprints.nottingham.ac.uk/46944/ Nickel(II) metal-organic frameworks with N,N’-di(4-pyridyl)-1,4,5,8-naphthalenetetracarboxydiimide ligands: influence of secondary building unit geometry on dimensionality and framework dimensions Pfeiffer, Constance R. Biggins, Naomi H. Lewis, William Champness, Neil R. When Ni(NO3)2∙6H2O and N,N’-di(4-pyridyl)-1,4,5,8-naphthalenetetracarboxydiimide (DPNDI) are reacted, a one-dimensional coordination polymer (1) is formed. However, reaction with either terephthalic acid (2) or 2,6-naphthalenedicarboxylic acid (3) affords two-dimensional, pillared metal-organic frameworks. 2 and 3 containing rectangular voids of different dimensions which are dictated by the carboxylate ligand and the arrangement of the [M(k2-O2NO)]2(μ2-O2CR)2] secondary building unit (SBU) that forms the nodes of the framework. The role of SBU geometry, intermolecular face-to-face π–π and lone pair–π interactions involving the DPNDI ligands are discussed. Royal Society of Chemistry 2017-09-05 Article PeerReviewed Pfeiffer, Constance R., Biggins, Naomi H., Lewis, William and Champness, Neil R. (2017) Nickel(II) metal-organic frameworks with N,N’-di(4-pyridyl)-1,4,5,8-naphthalenetetracarboxydiimide ligands: influence of secondary building unit geometry on dimensionality and framework dimensions. CrystEngComm, 19 . pp. 5559-5564. ISSN 1466-8033 Metal-organic frameworks N N’-di(4-pyridyl)-1 4 5 8-naphthalenetetracarboxydiimide nickel (II) frameworks pillared frameworks http://pubs.rsc.org/en/content/articlelanding/2017/ce/c7ce00956a#!divAbstract doi:10.1039/C7CE00956A doi:10.1039/C7CE00956A |
| spellingShingle | Metal-organic frameworks N N’-di(4-pyridyl)-1 4 5 8-naphthalenetetracarboxydiimide nickel (II) frameworks pillared frameworks Pfeiffer, Constance R. Biggins, Naomi H. Lewis, William Champness, Neil R. Nickel(II) metal-organic frameworks with N,N’-di(4-pyridyl)-1,4,5,8-naphthalenetetracarboxydiimide ligands: influence of secondary building unit geometry on dimensionality and framework dimensions |
| title | Nickel(II) metal-organic frameworks with N,N’-di(4-pyridyl)-1,4,5,8-naphthalenetetracarboxydiimide ligands: influence of secondary building unit geometry on dimensionality and framework dimensions |
| title_full | Nickel(II) metal-organic frameworks with N,N’-di(4-pyridyl)-1,4,5,8-naphthalenetetracarboxydiimide ligands: influence of secondary building unit geometry on dimensionality and framework dimensions |
| title_fullStr | Nickel(II) metal-organic frameworks with N,N’-di(4-pyridyl)-1,4,5,8-naphthalenetetracarboxydiimide ligands: influence of secondary building unit geometry on dimensionality and framework dimensions |
| title_full_unstemmed | Nickel(II) metal-organic frameworks with N,N’-di(4-pyridyl)-1,4,5,8-naphthalenetetracarboxydiimide ligands: influence of secondary building unit geometry on dimensionality and framework dimensions |
| title_short | Nickel(II) metal-organic frameworks with N,N’-di(4-pyridyl)-1,4,5,8-naphthalenetetracarboxydiimide ligands: influence of secondary building unit geometry on dimensionality and framework dimensions |
| title_sort | nickel(ii) metal-organic frameworks with n,n’-di(4-pyridyl)-1,4,5,8-naphthalenetetracarboxydiimide ligands: influence of secondary building unit geometry on dimensionality and framework dimensions |
| topic | Metal-organic frameworks N N’-di(4-pyridyl)-1 4 5 8-naphthalenetetracarboxydiimide nickel (II) frameworks pillared frameworks |
| url | https://eprints.nottingham.ac.uk/46944/ https://eprints.nottingham.ac.uk/46944/ https://eprints.nottingham.ac.uk/46944/ |