Probing the nature and reactivity of coordination complexes with blended organic and inorganic chromophores using vibrational spectroscopy
The use of transient vibrational spectroscopy in the analysis of rhenium(I) and ruthenium(II) complexes is discussed. Particular focus is given to the use resonance Raman spectroscopy to probe initial photoexcitation and transient resonance Raman and infrared spectroscopy to observe subsequent relax...
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| Format: | Article |
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Elsevier
2016
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| Online Access: | https://eprints.nottingham.ac.uk/46820/ |
| _version_ | 1848797406262460416 |
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| author | Horvath, Raphael Huff, Gregory S. Gordon, Keith C. George, Michael W. |
| author_facet | Horvath, Raphael Huff, Gregory S. Gordon, Keith C. George, Michael W. |
| author_sort | Horvath, Raphael |
| building | Nottingham Research Data Repository |
| collection | Online Access |
| description | The use of transient vibrational spectroscopy in the analysis of rhenium(I) and ruthenium(II) complexes is discussed. Particular focus is given to the use resonance Raman spectroscopy to probe initial photoexcitation and transient resonance Raman and infrared spectroscopy to observe subsequent relaxation processes. The utility of these techniques is given by discussion of examples in which the electronic complexity of the system increases from systems which are nominally pure metal-to-ligand charge-transfer through to systems which have complex interplay between intraligand and metal-to-ligand charge transfer states. The use of these later systems in dye-sensitised solar cells is also briefly discussed. |
| first_indexed | 2025-11-14T20:03:22Z |
| format | Article |
| id | nottingham-46820 |
| institution | University of Nottingham Malaysia Campus |
| institution_category | Local University |
| last_indexed | 2025-11-14T20:03:22Z |
| publishDate | 2016 |
| publisher | Elsevier |
| recordtype | eprints |
| repository_type | Digital Repository |
| spelling | nottingham-468202020-05-04T18:16:57Z https://eprints.nottingham.ac.uk/46820/ Probing the nature and reactivity of coordination complexes with blended organic and inorganic chromophores using vibrational spectroscopy Horvath, Raphael Huff, Gregory S. Gordon, Keith C. George, Michael W. The use of transient vibrational spectroscopy in the analysis of rhenium(I) and ruthenium(II) complexes is discussed. Particular focus is given to the use resonance Raman spectroscopy to probe initial photoexcitation and transient resonance Raman and infrared spectroscopy to observe subsequent relaxation processes. The utility of these techniques is given by discussion of examples in which the electronic complexity of the system increases from systems which are nominally pure metal-to-ligand charge-transfer through to systems which have complex interplay between intraligand and metal-to-ligand charge transfer states. The use of these later systems in dye-sensitised solar cells is also briefly discussed. Elsevier 2016-10-15 Article PeerReviewed Horvath, Raphael, Huff, Gregory S., Gordon, Keith C. and George, Michael W. (2016) Probing the nature and reactivity of coordination complexes with blended organic and inorganic chromophores using vibrational spectroscopy. Coordination Chemistry Reviews, 325 . pp. 41-58. ISSN 0010-8545 Blended organic and inorganic chromophores; Transient spectroscopy; Coordination compounds http://www.sciencedirect.com/science/article/pii/S001085451630100X doi:10.1016/j.ccr.2016.04.007 doi:10.1016/j.ccr.2016.04.007 |
| spellingShingle | Blended organic and inorganic chromophores; Transient spectroscopy; Coordination compounds Horvath, Raphael Huff, Gregory S. Gordon, Keith C. George, Michael W. Probing the nature and reactivity of coordination complexes with blended organic and inorganic chromophores using vibrational spectroscopy |
| title | Probing the nature and reactivity of coordination complexes with blended organic and inorganic chromophores using vibrational spectroscopy |
| title_full | Probing the nature and reactivity of coordination complexes with blended organic and inorganic chromophores using vibrational spectroscopy |
| title_fullStr | Probing the nature and reactivity of coordination complexes with blended organic and inorganic chromophores using vibrational spectroscopy |
| title_full_unstemmed | Probing the nature and reactivity of coordination complexes with blended organic and inorganic chromophores using vibrational spectroscopy |
| title_short | Probing the nature and reactivity of coordination complexes with blended organic and inorganic chromophores using vibrational spectroscopy |
| title_sort | probing the nature and reactivity of coordination complexes with blended organic and inorganic chromophores using vibrational spectroscopy |
| topic | Blended organic and inorganic chromophores; Transient spectroscopy; Coordination compounds |
| url | https://eprints.nottingham.ac.uk/46820/ https://eprints.nottingham.ac.uk/46820/ https://eprints.nottingham.ac.uk/46820/ |