Graphene/zinc oxide nanocomposite : a versatile platform for electrochemical-based genosensor

In this work, a versatile electrochemical biosensing platform was developed based on graphene/zinc oxide (G/ZnO) nanocomposite. For the synthesis of G/ZnO nanocomposite, two facile and green approaches were employed to eradicate the issues associated with conventional methods, which use harsh chemic...

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Main Author: Low, Sze Shin
Format: Thesis (University of Nottingham only)
Language:English
Published: 2018
Subjects:
Online Access:https://eprints.nottingham.ac.uk/46795/
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author Low, Sze Shin
author_facet Low, Sze Shin
author_sort Low, Sze Shin
building Nottingham Research Data Repository
collection Online Access
description In this work, a versatile electrochemical biosensing platform was developed based on graphene/zinc oxide (G/ZnO) nanocomposite. For the synthesis of G/ZnO nanocomposite, two facile and green approaches were employed to eradicate the issues associated with conventional methods, which use harsh chemicals and high temperature. The G/ZnO nanocomposite synthesised via low temperature hydrothermal growth method exhibited approximate 58 times improvement in terms of sensitivity as compared to the G/ZnO nanocomposite synthesised via the mechanical stirring method. Therefore, the G/ZnO nanocomposite with higher sensitivity was employed for the following work. Results from cyclic voltammetry and amperometry showed that the G/ZnO-modified electrode displayed a wide linear range up to 15 mM for the detection of H2O2 and sensitivity improvements of 200% in comparison to the control sample. Subsequently, an electrochemical genosensor based on G/ZnO nanocomposite was fabricated for the detection of Avian Influenza H5N1 virus. The G/ZnO-based genosensor displayed its potential in replacing the conventional detection method, with result showing higher sensitivity and efficiency. The G/ZnO-based genosensor was further applied for the detection of Coconut Cadang-Cadang Viroid disease (CCCVd) single stranded RNA (ssRNA). Promising results were obtained with high specificity in discriminating the target from mismatched ssRNA sequences.
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spelling nottingham-467952025-02-28T11:59:04Z https://eprints.nottingham.ac.uk/46795/ Graphene/zinc oxide nanocomposite : a versatile platform for electrochemical-based genosensor Low, Sze Shin In this work, a versatile electrochemical biosensing platform was developed based on graphene/zinc oxide (G/ZnO) nanocomposite. For the synthesis of G/ZnO nanocomposite, two facile and green approaches were employed to eradicate the issues associated with conventional methods, which use harsh chemicals and high temperature. The G/ZnO nanocomposite synthesised via low temperature hydrothermal growth method exhibited approximate 58 times improvement in terms of sensitivity as compared to the G/ZnO nanocomposite synthesised via the mechanical stirring method. Therefore, the G/ZnO nanocomposite with higher sensitivity was employed for the following work. Results from cyclic voltammetry and amperometry showed that the G/ZnO-modified electrode displayed a wide linear range up to 15 mM for the detection of H2O2 and sensitivity improvements of 200% in comparison to the control sample. Subsequently, an electrochemical genosensor based on G/ZnO nanocomposite was fabricated for the detection of Avian Influenza H5N1 virus. The G/ZnO-based genosensor displayed its potential in replacing the conventional detection method, with result showing higher sensitivity and efficiency. The G/ZnO-based genosensor was further applied for the detection of Coconut Cadang-Cadang Viroid disease (CCCVd) single stranded RNA (ssRNA). Promising results were obtained with high specificity in discriminating the target from mismatched ssRNA sequences. 2018-02-24 Thesis (University of Nottingham only) NonPeerReviewed application/pdf en arr https://eprints.nottingham.ac.uk/46795/1/PhD%20Thesis%20%28edited%29%20-%20Low%20Sze%20Shin.pdf Low, Sze Shin (2018) Graphene/zinc oxide nanocomposite : a versatile platform for electrochemical-based genosensor. PhD thesis, University of Nottingham. biosensors nanocomposites graphene nanotubes
spellingShingle biosensors
nanocomposites
graphene
nanotubes
Low, Sze Shin
Graphene/zinc oxide nanocomposite : a versatile platform for electrochemical-based genosensor
title Graphene/zinc oxide nanocomposite : a versatile platform for electrochemical-based genosensor
title_full Graphene/zinc oxide nanocomposite : a versatile platform for electrochemical-based genosensor
title_fullStr Graphene/zinc oxide nanocomposite : a versatile platform for electrochemical-based genosensor
title_full_unstemmed Graphene/zinc oxide nanocomposite : a versatile platform for electrochemical-based genosensor
title_short Graphene/zinc oxide nanocomposite : a versatile platform for electrochemical-based genosensor
title_sort graphene/zinc oxide nanocomposite : a versatile platform for electrochemical-based genosensor
topic biosensors
nanocomposites
graphene
nanotubes
url https://eprints.nottingham.ac.uk/46795/