Uranium Metalla-Allenes with Carbene Imido R2C=UIV=NR′ Units (R=Ph2PNSiMe3; R′=CPh3): Alkali-Metal-Mediated push–pull effects with an Amido Auxiliary

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Uranium Metalla-Allenes with Carbene Imido R2C=UIV=NR′ Units (R=Ph2PNSiMe3; R′=CPh3): Alkali-Metal-Mediated push–pull effects with an Amido Auxiliary

We report uranium(IV)-carbene-imido-amide metalla-allene complexes [U(BIPMTMS)(NCPh3)(NHCPh3)(M)] (BIPMTMS=C(PPh2NSiMe3)2; M=Li or K) that can be described as R2C=U=NR′ push–pull metalla-allene units, as organometallic counterparts of the well-known push–pull organic allenes. The solid-state structu...

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Bibliographic Details
Main Authors:	Lu, Erli, Tuna, Floriana, Lewis, William, Kaltsoyannis, Nikolas, Liddle, Stephen T.
Format:	Article
Published:	Wiley 2016
Online Access:	https://eprints.nottingham.ac.uk/46649/

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