Terminal uranium(V/VI) nitride activation of carbon dioxide and carbon disulfide: factors governing diverse and well-defined cleavage and redox reactions

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Terminal uranium(V/VI) nitride activation of carbon dioxide and carbon disulfide: factors governing diverse and well-defined cleavage and redox reactions

The reactivity of terminal uranium(V/VI) nitrides with CE2 (E=O, S) is presented. Well-defined C=E cleavage followed by zero-, one-, and two-electron redox events is observed. The uranium(V) nitride [U(TrenTIPS)(N)][K(B15C5)2] (1, TrenTIPS=N(CH2CH2NSiiPr3)3; B15C5=benzo-15-crown-5) reacts with CO2 t...

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Bibliographic Details
Main Authors:	Cleaves, Peter A., Kefalidis, Christos E., Gardner, Benedict M., Tuna, Floriana, McInnes, Eric J.L., Lewis, William, Maron, Laurent, Liddle, Stephen T.
Format:	Article
Published:	Wiley-VCH Verlag 2017
Subjects:	carbon dioxide; carbon disulfide; density functional theory; nitride; uranium
Online Access:	https://eprints.nottingham.ac.uk/46648/

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