Isolation of stable non cyclic 1,2-disulfoxides: revisiting the thermolysis of S-aryl sulfinimines
The thermolysis of S-aryl sulfinimines is shown to generate 1,2-disulfoxides and disulfides via initial Cope elimination, dimerisation of the produced sulfenic acid to a thiosulfinate, and subsequent disproportionation of the thiosulfinate.
| Main Authors: | , , |
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| Format: | Article |
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Royal Society of Chemistry
2014
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| Online Access: | https://eprints.nottingham.ac.uk/46644/ |
| _version_ | 1848797376071860224 |
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| author | Souto, José A. Lewis, William Stockman, Robert A. |
| author_facet | Souto, José A. Lewis, William Stockman, Robert A. |
| author_sort | Souto, José A. |
| building | Nottingham Research Data Repository |
| collection | Online Access |
| description | The thermolysis of S-aryl sulfinimines is shown to generate 1,2-disulfoxides and disulfides via initial Cope elimination, dimerisation of the produced sulfenic acid to a thiosulfinate, and subsequent disproportionation of the thiosulfinate. |
| first_indexed | 2025-11-14T20:02:53Z |
| format | Article |
| id | nottingham-46644 |
| institution | University of Nottingham Malaysia Campus |
| institution_category | Local University |
| last_indexed | 2025-11-14T20:02:53Z |
| publishDate | 2014 |
| publisher | Royal Society of Chemistry |
| recordtype | eprints |
| repository_type | Digital Repository |
| spelling | nottingham-466442020-05-04T16:51:45Z https://eprints.nottingham.ac.uk/46644/ Isolation of stable non cyclic 1,2-disulfoxides: revisiting the thermolysis of S-aryl sulfinimines Souto, José A. Lewis, William Stockman, Robert A. The thermolysis of S-aryl sulfinimines is shown to generate 1,2-disulfoxides and disulfides via initial Cope elimination, dimerisation of the produced sulfenic acid to a thiosulfinate, and subsequent disproportionation of the thiosulfinate. Royal Society of Chemistry 2014-09-01 Article PeerReviewed Souto, José A., Lewis, William and Stockman, Robert A. (2014) Isolation of stable non cyclic 1,2-disulfoxides: revisiting the thermolysis of S-aryl sulfinimines. Chemical Communications, 50 (84). pp. 12630-12632. ISSN 1364-548X http://pubs.rsc.org/en/Content/ArticleLanding/2014/CC/C4CC05751A#!divAbstract doi:10.1039/c4cc05751a doi:10.1039/c4cc05751a |
| spellingShingle | Souto, José A. Lewis, William Stockman, Robert A. Isolation of stable non cyclic 1,2-disulfoxides: revisiting the thermolysis of S-aryl sulfinimines |
| title | Isolation of stable non cyclic 1,2-disulfoxides: revisiting the thermolysis of S-aryl sulfinimines |
| title_full | Isolation of stable non cyclic 1,2-disulfoxides: revisiting the thermolysis of S-aryl sulfinimines |
| title_fullStr | Isolation of stable non cyclic 1,2-disulfoxides: revisiting the thermolysis of S-aryl sulfinimines |
| title_full_unstemmed | Isolation of stable non cyclic 1,2-disulfoxides: revisiting the thermolysis of S-aryl sulfinimines |
| title_short | Isolation of stable non cyclic 1,2-disulfoxides: revisiting the thermolysis of S-aryl sulfinimines |
| title_sort | isolation of stable non cyclic 1,2-disulfoxides: revisiting the thermolysis of s-aryl sulfinimines |
| url | https://eprints.nottingham.ac.uk/46644/ https://eprints.nottingham.ac.uk/46644/ https://eprints.nottingham.ac.uk/46644/ |