The ketimide ligand is not just an inert spectator: heteroallene insertion reactivity of an actinide-ketimide linkage in a thorium carbene amide ketimide complex

QR Code

The ketimide ligand is not just an inert spectator: heteroallene insertion reactivity of an actinide-ketimide linkage in a thorium carbene amide ketimide complex

The ketimide anion R2C[DOUBLE BOND]N− is an important class of chemically robust ligand that binds strongly to metal ions and is considered ideal for supporting reactive metal fragments due to its inert spectator nature; this contrasts with R2N− amides that exhibit a wide range of reactivities. Here...

Full description

Bibliographic Details
Main Authors:	Lu, Erli, Lewis, William, Blake, Alexander J., Liddle, Stephen T.
Format:	Article
Published:	Wiley-VCH Verlag 2014
Subjects:	amides; carbenes; ketimides; N ligands; thorium
Online Access:	https://eprints.nottingham.ac.uk/46640/

Similar Items

Synthesis, characterization, and reactivity of a uranium(VI) carbene imido oxo complex
by: Lu, Erli, et al.
Published: (2014)

Actinide coordination chemistry - a unique example of a homoleptic complex of nine-coordinate thorium(IV)
by: Harrowfield, J., et al.
Published: (2004)

Preparation of Fatty Amides from Metal Soaps Under Microwave Irradiation
by: Lee, Yean Kee
Published: (2002)

N-Heterocyclic carbenes as π*-acceptors in luminescent Re(I) triscarbonyl complexes
by: Casson, L., et al.
Published: (2011)

Lipase-catalysed synthesis and optimization of biologically active amides of cinnamic acid derivatives
by: Abu Alrub, Mohammad Hesham Abdelrahman
Published: (2013)

New methods for the construction of fluorinated cyclic amines and amides
by: Charlesworth, Natalie
Published: (2022)

The inverse-trans-influence in tetravalent lanthanide and actinide bis(carbene) complexes
by: Gregson, Matthew, et al.
Published: (2017)

Planar Chiral Ferrocene Lithium Amide Bases: A New Generation of Bases for Asymmetric Synthesis
by: Arnall-Culliford, Jennifer
Published: (2002)

Synthesis of Fatty and N,N'-carbonyl Difatty Amides from Palm Oil and Their Applications as a Clay Modifier for Polylactic Acid/Epoxidized Palm Oil/Clay Nanocomposites Preparation
by: Jaffar Al-Mulla, Emad A.
Published: (2010)

Developing Carbene Footprinting Mass Spectrometry to Interrogate Protein-Ligand Interactions
by: Lloyd, James
Published: (2023)

Synthesis and Characterisation of Mono- and Bidentate Alkoxybenzimidazolin-2-ylidene Palladium Complexes: Interesting Solution Behaviour and Application in Catalysis
by: Simpson, P., et al.
Published: (2011)

Identification and optimisation of lipase- catalysed synthesis of betulinic acid amide in a solvent system
by: Amin Yusof, Nurul Atikah, et al.
Published: (2016)

Silver(I) and mercury(II) complexes of meta- and para-xylyl linked bis(imidazol-2-ylidenes)
by: Baker, M., et al.
Published: (2009)

Carbene footprinting reveals binding interfaces of a multimeric membrane spanning protein
by: Manzi, Lucio, et al.
Published: (2017)

Carbene in cupredoxin protein scaffolds: replacement of a histidine ligand in the active site substantially alters copper redox properties
by: Planchestainer, Matteo, et al.
Published: (2018)

The synthesis and characterisations of porous thioamide- sulfonated-modified poly (acrylonitrile-co- divinylbenzene-80) as potential sorbent to capture polar analytes
by: Ismail, Farhana Syakirah
Published: (2019)

Single-Carbon Atom Insertion into Aromatic Heterocycles
by: Joynson, Ben
Published: (2023)

Alkaline earth complexes of a sterically demanding guanidinate ligand
by: Moxey, Graeme J., et al.
Published: (2015)

Phase Decomposition upon Alteration of Radiation-Damaged Monazite-(Ce) from Moss, Ostfold, Norway
by: Nasdala, L., et al.
Published: (2010)

Synthesis of low co-ordinate heteroleptic first row transition metal complexes
by: Churchill, Olivia
Published: (2019)

Sterically demanding pincer ligands for transition metal chemistry
by: Albelwe, Bayan L.
Published: (2025)

Synthesis, characterization, and bioactivities of dithiocarbazate-Schiff base ligands and their metal complexes
by: Low, May Lee
Published: (2014)

Investigation of epimer formation in amide coupling reactions: an experiment for advanced undergraduate students
by: Fray, Michael J.
Published: (2014)

Total synthesis of the post-translationally modified polyazole peptide antibiotic plantazolicin A
by: Wada, Hiroki, et al.
Published: (2015)

Stereoselective synthesis of functionalized pyrrolidines by the diverted NH insertion reaction of metallocarbenes with β-aminoketone derivatives
by: Nicolle, Simon M., et al.
Published: (2016)

Measuring ligand concentration where it matters: Assessing the “micro pharmacokinetic/pharmacodynamics” of adenosine receptor ligands
by: Lochray, Jack
Published: (2022)

Geometric adventures with self-assembled metal-ligand coordination structures
by: Fan, Yucong
Published: (2024)

Actinide and non-actinide production from UO2 fuel in W-SMR: Effects of gadolinium burnable absorber
by: Uguru, E. H., et al.
Published: (2020)

Ways of spectating: unravelling spectator participation in Kinect play
by: Tekin, Burak S., et al.
Published: (2017)

The Enantioselective Generation of Bridgehead Enolates
by: Kirk, Douglas Thomas
Published: (2003)

New preparations of diazo compounds and studies of their metal catalysed diverted insertion reactions
by: Nicolle, Simon
Published: (2016)

Synthesis and Complexation of a Bulky Silyl Phosphanide and Extended PNNNP Carbazole-based Ligand
by: Churchill, Olivia
Published: (2024)

Synthesis, characterization and biological activities of tridentate ons Schiff bases and their mixed-ligand metal complexes containing imidazole or benzimidazole
by: Mazlan, Nurul Ain
Published: (2014)

Stereoselective synthesis of tetrahydroindolizines via catalytic formation of pyridinium ylides from diazo compounds
by: Day, Jonathan, et al.
Published: (2016)

Synthesis, reactivity and preliminary biological activity of iron(0) complexes with cyclopentadienone and amino-appended N-heterocyclic carbene ligands
by: Cingolani, A., et al.
Published: (2019)

Designing the spectator experience
by: Reeves, Stuart, et al.
Published: (2005)

Analysis of high and selective uptake of CO2 in an oxamide-containing {Cu2(OOCR)4}-based metal-organic framework
by: Alsmail, Nada H., et al.
Published: (2014)

Gabapentinoid use, risks, and the impact of reclassification for chronic pain patients in the United Kingdom
by: ALFRIAH, JOUD
Published: (2024)

Sugar Coated Formulations
by: Takan, Gokhan
Published: (2024)

Design, synthesis, characterisation and optimisation for titanium complexes for anti-cancer activity
by: Musa, Mustapha
Published: (2023)