The ketimide ligand is not just an inert spectator: heteroallene insertion reactivity of an actinide-ketimide linkage in a thorium carbene amide ketimide complex
The ketimide anion R2C[DOUBLE BOND]N− is an important class of chemically robust ligand that binds strongly to metal ions and is considered ideal for supporting reactive metal fragments due to its inert spectator nature; this contrasts with R2N− amides that exhibit a wide range of reactivities. Here...
| Main Authors: | , , , |
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| Format: | Article |
| Published: |
Wiley-VCH Verlag
2014
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| Subjects: | |
| Online Access: | https://eprints.nottingham.ac.uk/46640/ |