Synthesis, characterization, and reactivity of a uranium(VI) carbene imido oxo complex

Synthesis, characterization, and reactivity of a uranium(VI) carbene imido oxo complex

We report the uranium(VI) carbene imido oxo complex [U(BIPMTMS)(NMes)(O)(DMAP)2] (5, BIPMTMS=C(PPh2NSiMe3)2; Mes=2,4,6-Me3C6H2; DMAP=4-(dimethylamino)pyridine) which exhibits the unprecedented arrangement of three formal multiply bonded ligands to one metal center where the coordinated heteroatoms d...

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Bibliographic Details
Main Authors: Lu, Erli, Cooper, Oliver J., McMaster, Jonathan, Tuna, Floriana, McInnes, Eric J.L., Lewis, William, Blake, Alexander J., Liddle, Stephen T.
Format: Article
Published: Wiley-VCH Verlag 2014
Subjects:
carbene ligands; imido ligands; multiple bonding; oxo ligands; uranium
Online Access:https://eprints.nottingham.ac.uk/46639/

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https://eprints.nottingham.ac.uk/46639/

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