Triamidoamine-uranium(IV)-stabilized terminal parent phosphide and phosphinidene complexes

Triamidoamine-uranium(IV)-stabilized terminal parent phosphide and phosphinidene complexes

Reaction of [U(TrenTIPS)(THF)][BPh4] (1; TrenTIPS=N{CH2CH2NSi(iPr)3}3) with NaPH2 afforded the novel f-block terminal parent phosphide complex [U(TrenTIPS)(PH2)] (2; U–P=2.883(2) Å). Treatment of 2 with one equivalent of KCH2C6H5 and two equivalents of benzo-15-crown-5 ether (B15C5) afforded the unp...

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Bibliographic Details
Main Authors: Gardner, Benedict M., Balázs, Gábor, Scheer, Manfred, Tuna, Floriana, McInnes, Eric J.L., McMaster, Jonathan, Lewis, William, Blake, Alexander J., Liddle, Stephen T.
Format: Article
Published: Wiley-VCH Verlag 2014
Subjects:
density functional calculations; multiple bonds; phosphides; phosphinidene; uranium
Online Access:https://eprints.nottingham.ac.uk/46636/

Internet

https://eprints.nottingham.ac.uk/46636/

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