Two-electron reductive carbonylation of terminal uranium(V) and uranium(VI) nitrides to cyanate by carbon monoxide

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Two-electron reductive carbonylation of terminal uranium(V) and uranium(VI) nitrides to cyanate by carbon monoxide

Two-electron reductive carbonylation of the uranium(VI) nitride [U(TrenTIPS)(N)] (2, TrenTIPS=N(CH2CH2NSiiPr3)3) with CO gave the uranium(IV) cyanate [U(TrenTIPS)(NCO)] (3). KC8 reduction of 3 resulted in cyanate dissociation to give [U(TrenTIPS)] (4) and KNCO, or cyanate retention in [U(TrenTIPS)(N...

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Bibliographic Details
Main Authors:	Cleaves, Peter A., King, David M., Kefalidis, Christos E., Maron, Laurent, Tuna, Floriana, McInnes, Eric J.L., McMaster, Jonathan, Lewis, William, Blake, Alexander J., Liddle, Stephen T.
Format:	Article
Published:	Wiley-VCH Verlag 2014
Subjects:	carbon monoxide; carbonylation; cyanates; nitrides; uranium
Online Access:	https://eprints.nottingham.ac.uk/46634/

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