X-ray photoelectron spectroscopy as a probe of rhodium-ligand interaction in ionic liquids

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X-ray photoelectron spectroscopy as a probe of rhodium-ligand interaction in ionic liquids

We use X-ray photoelectron spectroscopy (XPS) to identify the interaction between the rhodium atom and phosphine ligands in six 1-octyl-3-methylimidazolium-based ionic liquids ([C8C1Im][X]). The formation of a mono-phosphine rhodium complex based upon addition of triphenylphosphine (PPh3) is confirm...

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Bibliographic Details
Main Authors:	Men, Shuan, Lovelock, Kevin, Licence, Peter
Format:	Article
Published:	Elsevier 2016
Subjects:	Ionic liquids Phosphine ligands Rhodium atom Biphosphine ligand Chelated diphosphine rhodium complex
Online Access:	https://eprints.nottingham.ac.uk/45497/

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