Core/clad phosphate glass fibres containing iron and/or titanium

Phosphate glasses are novel amorphous biomaterials due to their fully resorbable characteristics, with controllable degradation profiles. In this study, phosphate glasses containing titanium and/or iron were identified to exhibit sufficiently matched thermal properties (glass transition temperature,...

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Main Authors: Ahmed, Ifty, Shahruddin, Sharifah, Sharmin, Nusrat, Furniss, David, Rudd, Chris D.
Format: Article
Published: De Gruyter Open 2015
Online Access:https://eprints.nottingham.ac.uk/45107/
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author Ahmed, Ifty
Shahruddin, Sharifah
Sharmin, Nusrat
Furniss, David
Rudd, Chris D.
author_facet Ahmed, Ifty
Shahruddin, Sharifah
Sharmin, Nusrat
Furniss, David
Rudd, Chris D.
author_sort Ahmed, Ifty
building Nottingham Research Data Repository
collection Online Access
description Phosphate glasses are novel amorphous biomaterials due to their fully resorbable characteristics, with controllable degradation profiles. In this study, phosphate glasses containing titanium and/or iron were identified to exhibit sufficiently matched thermal properties (glass transition temperature, thermal expansion coefficient and viscosity) which enabled successful co-extrusion of glass billets to form a core/clad preform. The cladding composition for the core/clad preforms were also reversed. Fe clad and Ti clad fibres were successfully drawn with an average diameter of between 30~50 μm. The average cladding annular thickness was estimated to be less than 2 μm. Annealed core/clad fibres were degraded in PBS for a period of 27 days. The strength of the Fe clad fibres appeared to increase from 303 ± 73 MPa to 386 ± 45 MPa after nearly 2 weeks in the dissolution medium (phosphate buffered solution) before decreasing by day 27. The strength of the Ti clad fibres revealed an increase from 236 ± 53 MPa to 295 ± 61 MPa when compared at week 3. The tensile modulus measured for both core/clad fibres ranged between 51 GPa to 60 GPa. During the dissolution study, Fe clad fibres showed a peeling mechanism compared to the Ti clad fibres.
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institution University of Nottingham Malaysia Campus
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spelling nottingham-451072020-05-04T17:12:36Z https://eprints.nottingham.ac.uk/45107/ Core/clad phosphate glass fibres containing iron and/or titanium Ahmed, Ifty Shahruddin, Sharifah Sharmin, Nusrat Furniss, David Rudd, Chris D. Phosphate glasses are novel amorphous biomaterials due to their fully resorbable characteristics, with controllable degradation profiles. In this study, phosphate glasses containing titanium and/or iron were identified to exhibit sufficiently matched thermal properties (glass transition temperature, thermal expansion coefficient and viscosity) which enabled successful co-extrusion of glass billets to form a core/clad preform. The cladding composition for the core/clad preforms were also reversed. Fe clad and Ti clad fibres were successfully drawn with an average diameter of between 30~50 μm. The average cladding annular thickness was estimated to be less than 2 μm. Annealed core/clad fibres were degraded in PBS for a period of 27 days. The strength of the Fe clad fibres appeared to increase from 303 ± 73 MPa to 386 ± 45 MPa after nearly 2 weeks in the dissolution medium (phosphate buffered solution) before decreasing by day 27. The strength of the Ti clad fibres revealed an increase from 236 ± 53 MPa to 295 ± 61 MPa when compared at week 3. The tensile modulus measured for both core/clad fibres ranged between 51 GPa to 60 GPa. During the dissolution study, Fe clad fibres showed a peeling mechanism compared to the Ti clad fibres. De Gruyter Open 2015-07-20 Article PeerReviewed Ahmed, Ifty, Shahruddin, Sharifah, Sharmin, Nusrat, Furniss, David and Rudd, Chris D. (2015) Core/clad phosphate glass fibres containing iron and/or titanium. Biomedical Glasses, 1 (1). pp. 20-30. ISSN 2299-3932 https://www.degruyter.com/view/j/bglass.2015.1.issue-1/bglass-2015-0004/bglass-2015-0004.xml doi:10.1515/bglass-2015-0004 doi:10.1515/bglass-2015-0004
spellingShingle Ahmed, Ifty
Shahruddin, Sharifah
Sharmin, Nusrat
Furniss, David
Rudd, Chris D.
Core/clad phosphate glass fibres containing iron and/or titanium
title Core/clad phosphate glass fibres containing iron and/or titanium
title_full Core/clad phosphate glass fibres containing iron and/or titanium
title_fullStr Core/clad phosphate glass fibres containing iron and/or titanium
title_full_unstemmed Core/clad phosphate glass fibres containing iron and/or titanium
title_short Core/clad phosphate glass fibres containing iron and/or titanium
title_sort core/clad phosphate glass fibres containing iron and/or titanium
url https://eprints.nottingham.ac.uk/45107/
https://eprints.nottingham.ac.uk/45107/
https://eprints.nottingham.ac.uk/45107/