Synthesis, crystal structures and magnetic properties of composites incorporating an Fe(II) spin crossover complex and polyoxometalates

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Synthesis, crystal structures and magnetic properties of composites incorporating an Fe(II) spin crossover complex and polyoxometalates

[Fe(dppOH)2]2+ (dppOH = 2,6-di(pyrazol-1-yl)-4-(hydroxymethyl)pyridine) is known to show spin crossover (SCO) behavior and light-induced excited spin state transitions (LIESST). Here, we show that the SCO properties of the [Fe(dppOH)2]2+ complex can be altered by a crystal engineering approach emplo...

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Bibliographic Details
Main Authors:	Kuramochi, Satoshi, Shiga, Takuya, Cameron, Jamie M., Newton, Graham N., Oshio, Hiroki
Format:	Article
Published:	MDPI 2017
Subjects:	Spin crossover; Polyoxometalate; Crystal engineering; Magnetic properties; Iron
Online Access:	https://eprints.nottingham.ac.uk/44459/

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