An antiferromagnetically coupled heterometal Cu6Fe wheel
A heterometal Cu6Fe wheel molecule, [CuII6FeIII(HL)6- (OH)2(OCH3)4](NO3)3¢6H2O (1¢6H2O) (H2L = 1-(2-pyridine) 3-(2-pyrrole)acetylacetone) was synthesized by the one-pot reaction of H2L with copper and iron sources. X-ray structural analysis reveals that the heptanuclear wheel cluster consists of a c...
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| Format: | Article |
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Chemical Society of Japan
2017
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| Online Access: | https://eprints.nottingham.ac.uk/44251/ |
| _version_ | 1848796872300298240 |
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| author | Saiki, Ryo Yoshida, Norifumi Hoshino, Norihisa Newton, Graham N. Shiga, Takuya Oshio, Hiroki |
| author_facet | Saiki, Ryo Yoshida, Norifumi Hoshino, Norihisa Newton, Graham N. Shiga, Takuya Oshio, Hiroki |
| author_sort | Saiki, Ryo |
| building | Nottingham Research Data Repository |
| collection | Online Access |
| description | A heterometal Cu6Fe wheel molecule, [CuII6FeIII(HL)6- (OH)2(OCH3)4](NO3)3¢6H2O (1¢6H2O) (H2L = 1-(2-pyridine) 3-(2-pyrrole)acetylacetone) was synthesized by the one-pot reaction of H2L with copper and iron sources. X-ray structural analysis reveals that the heptanuclear wheel cluster consists of a central Fe(III) ion surrounded by six Cu(II) ions, linked through methoxo- and hydroxo-bridges. Cryomagnetic studies indicate intramolecular antiferromagnetic interactions were operative. |
| first_indexed | 2025-11-14T19:54:53Z |
| format | Article |
| id | nottingham-44251 |
| institution | University of Nottingham Malaysia Campus |
| institution_category | Local University |
| last_indexed | 2025-11-14T19:54:53Z |
| publishDate | 2017 |
| publisher | Chemical Society of Japan |
| recordtype | eprints |
| repository_type | Digital Repository |
| spelling | nottingham-442512020-05-04T18:58:44Z https://eprints.nottingham.ac.uk/44251/ An antiferromagnetically coupled heterometal Cu6Fe wheel Saiki, Ryo Yoshida, Norifumi Hoshino, Norihisa Newton, Graham N. Shiga, Takuya Oshio, Hiroki A heterometal Cu6Fe wheel molecule, [CuII6FeIII(HL)6- (OH)2(OCH3)4](NO3)3¢6H2O (1¢6H2O) (H2L = 1-(2-pyridine) 3-(2-pyrrole)acetylacetone) was synthesized by the one-pot reaction of H2L with copper and iron sources. X-ray structural analysis reveals that the heptanuclear wheel cluster consists of a central Fe(III) ion surrounded by six Cu(II) ions, linked through methoxo- and hydroxo-bridges. Cryomagnetic studies indicate intramolecular antiferromagnetic interactions were operative. Chemical Society of Japan 2017-08-01 Article PeerReviewed Saiki, Ryo, Yoshida, Norifumi, Hoshino, Norihisa, Newton, Graham N., Shiga, Takuya and Oshio, Hiroki (2017) An antiferromagnetically coupled heterometal Cu6Fe wheel. Chemistry Letters, 46 (8). pp. 1197-1199. ISSN 0366-7022 Heterometal polynuclear complex ; Wheel complex ; Antiferromagnetic interaction http://www.journal.csj.jp/doi/abs/10.1246/cl.170365?af=R doi:10.1246/cl.170365 doi:10.1246/cl.170365 |
| spellingShingle | Heterometal polynuclear complex ; Wheel complex ; Antiferromagnetic interaction Saiki, Ryo Yoshida, Norifumi Hoshino, Norihisa Newton, Graham N. Shiga, Takuya Oshio, Hiroki An antiferromagnetically coupled heterometal Cu6Fe wheel |
| title | An antiferromagnetically coupled heterometal Cu6Fe wheel |
| title_full | An antiferromagnetically coupled heterometal Cu6Fe wheel |
| title_fullStr | An antiferromagnetically coupled heterometal Cu6Fe wheel |
| title_full_unstemmed | An antiferromagnetically coupled heterometal Cu6Fe wheel |
| title_short | An antiferromagnetically coupled heterometal Cu6Fe wheel |
| title_sort | antiferromagnetically coupled heterometal cu6fe wheel |
| topic | Heterometal polynuclear complex ; Wheel complex ; Antiferromagnetic interaction |
| url | https://eprints.nottingham.ac.uk/44251/ https://eprints.nottingham.ac.uk/44251/ https://eprints.nottingham.ac.uk/44251/ |