The impact of detergents on the tissue decellularization process: a ToF-SIMS study

Biologic scaffolds are derived from mammalian tissues, which must be decellularized to remove cellular antigens that would otherwise incite an adverse immune response. Although widely used clinically, the optimum balance between cell removal and the disruption of matrix architecture and surface liga...

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Main Authors: White, Lisa J., Taylor, Adam J., Faulk, Denver M., Keane, Timothy J., Saldin, Lindsey T., Reing, Janet E., Swinehart, Ilea T., Turner, Neill J., Ratner, Buddy D., Badylak, Stephen F.
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Published: Elsevier 2017
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Online Access:https://eprints.nottingham.ac.uk/44203/
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author White, Lisa J.
Taylor, Adam J.
Faulk, Denver M.
Keane, Timothy J.
Saldin, Lindsey T.
Reing, Janet E.
Swinehart, Ilea T.
Turner, Neill J.
Ratner, Buddy D.
Badylak, Stephen F.
author_facet White, Lisa J.
Taylor, Adam J.
Faulk, Denver M.
Keane, Timothy J.
Saldin, Lindsey T.
Reing, Janet E.
Swinehart, Ilea T.
Turner, Neill J.
Ratner, Buddy D.
Badylak, Stephen F.
author_sort White, Lisa J.
building Nottingham Research Data Repository
collection Online Access
description Biologic scaffolds are derived from mammalian tissues, which must be decellularized to remove cellular antigens that would otherwise incite an adverse immune response. Although widely used clinically, the optimum balance between cell removal and the disruption of matrix architecture and surface ligand landscape remains a considerable challenge. Here we describe the use of time of flight secondary ion mass spectroscopy (ToF-SIMS) to provide sensitive, molecular specific, localized analysis of detergent decellularized biologic scaffolds. We detected residual detergent fragments, specifically from Triton X-100, sodium deoxycholate and sodium dodecyl sulphate (SDS) in decellularized scaffolds; increased SDS concentrations from 0.1% to 1.0% increased both the intensity of SDS fragments and adverse cell outcomes. We also identified cellular remnants, by detecting phosphate and phosphocholine ions in PAA and CHAPS decellularized scaffolds. The present study demonstrates ToF-SIMS is not only a powerful tool for characterization of biologic scaffold surface molecular functionality, but also enables sensitive assessment of decellularization efficacy.
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spelling nottingham-442032020-05-04T18:32:55Z https://eprints.nottingham.ac.uk/44203/ The impact of detergents on the tissue decellularization process: a ToF-SIMS study White, Lisa J. Taylor, Adam J. Faulk, Denver M. Keane, Timothy J. Saldin, Lindsey T. Reing, Janet E. Swinehart, Ilea T. Turner, Neill J. Ratner, Buddy D. Badylak, Stephen F. Biologic scaffolds are derived from mammalian tissues, which must be decellularized to remove cellular antigens that would otherwise incite an adverse immune response. Although widely used clinically, the optimum balance between cell removal and the disruption of matrix architecture and surface ligand landscape remains a considerable challenge. Here we describe the use of time of flight secondary ion mass spectroscopy (ToF-SIMS) to provide sensitive, molecular specific, localized analysis of detergent decellularized biologic scaffolds. We detected residual detergent fragments, specifically from Triton X-100, sodium deoxycholate and sodium dodecyl sulphate (SDS) in decellularized scaffolds; increased SDS concentrations from 0.1% to 1.0% increased both the intensity of SDS fragments and adverse cell outcomes. We also identified cellular remnants, by detecting phosphate and phosphocholine ions in PAA and CHAPS decellularized scaffolds. The present study demonstrates ToF-SIMS is not only a powerful tool for characterization of biologic scaffold surface molecular functionality, but also enables sensitive assessment of decellularization efficacy. Elsevier 2017-03-01 Article PeerReviewed White, Lisa J., Taylor, Adam J., Faulk, Denver M., Keane, Timothy J., Saldin, Lindsey T., Reing, Janet E., Swinehart, Ilea T., Turner, Neill J., Ratner, Buddy D. and Badylak, Stephen F. (2017) The impact of detergents on the tissue decellularization process: a ToF-SIMS study. Acta Biomaterialia, 50 . pp. 207-219. ISSN 1878-7568 extracellular matrix biologic scaffold decellularization ToF-SIMS detergents http://www.sciencedirect.com/science/article/pii/S1742706116307012?via%3Dihub doi.org/10.1016/j.actbio.2016.12.033 doi.org/10.1016/j.actbio.2016.12.033
spellingShingle extracellular matrix
biologic scaffold
decellularization
ToF-SIMS
detergents
White, Lisa J.
Taylor, Adam J.
Faulk, Denver M.
Keane, Timothy J.
Saldin, Lindsey T.
Reing, Janet E.
Swinehart, Ilea T.
Turner, Neill J.
Ratner, Buddy D.
Badylak, Stephen F.
The impact of detergents on the tissue decellularization process: a ToF-SIMS study
title The impact of detergents on the tissue decellularization process: a ToF-SIMS study
title_full The impact of detergents on the tissue decellularization process: a ToF-SIMS study
title_fullStr The impact of detergents on the tissue decellularization process: a ToF-SIMS study
title_full_unstemmed The impact of detergents on the tissue decellularization process: a ToF-SIMS study
title_short The impact of detergents on the tissue decellularization process: a ToF-SIMS study
title_sort impact of detergents on the tissue decellularization process: a tof-sims study
topic extracellular matrix
biologic scaffold
decellularization
ToF-SIMS
detergents
url https://eprints.nottingham.ac.uk/44203/
https://eprints.nottingham.ac.uk/44203/
https://eprints.nottingham.ac.uk/44203/