Design and elaboration of a tractable tricyclic scaffold to synthesize druglike inhibitors of dipeptidyl peptidase-4 (DPP-4), antagonists of the C–C Chemokine Receptor Type 5 (CCR5), and highly potent and selective phosphoinositol-3 Kinase δ (PI3Kδ) inhibitors

A novel molecular scaffold has been synthesized, and its incorporation into new analogues of biologically active molecules across multiple target classes will be discussed. In these studies, we have shown use of the tricyclic scaffold to synthesize potent inhibitors of the serine peptidase DPP-4, an...

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Main Authors: Schwehm, Carolin, Kellam, Barrie, Garces, Aimie, Hill, Stephen J., Kindon, Nicholas, Bradshaw, Tracey D., Li, Jin, Macdonald, Simon J.F., Rowedder, James E., Stoddart, Leigh A., Stocks, Michael
Format: Article
Published: American Chemical Society 2017
Online Access:https://eprints.nottingham.ac.uk/44065/
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author Schwehm, Carolin
Kellam, Barrie
Garces, Aimie
Hill, Stephen J.
Kindon, Nicholas
Bradshaw, Tracey D.
Li, Jin
Macdonald, Simon J.F.
Rowedder, James E.
Stoddart, Leigh A.
Stocks, Michael
author_facet Schwehm, Carolin
Kellam, Barrie
Garces, Aimie
Hill, Stephen J.
Kindon, Nicholas
Bradshaw, Tracey D.
Li, Jin
Macdonald, Simon J.F.
Rowedder, James E.
Stoddart, Leigh A.
Stocks, Michael
author_sort Schwehm, Carolin
building Nottingham Research Data Repository
collection Online Access
description A novel molecular scaffold has been synthesized, and its incorporation into new analogues of biologically active molecules across multiple target classes will be discussed. In these studies, we have shown use of the tricyclic scaffold to synthesize potent inhibitors of the serine peptidase DPP-4, antagonists of the CCR5 receptor, and highly potent and selective PI3K δ isoform inhibitors. We also describe the predicted physicochemical properties of the resulting inhibitors and conclude that the tractable molecular scaffold could have potential application in future drug discovery programs.
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institution University of Nottingham Malaysia Campus
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last_indexed 2025-11-14T19:54:11Z
publishDate 2017
publisher American Chemical Society
recordtype eprints
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spelling nottingham-440652020-05-04T18:29:22Z https://eprints.nottingham.ac.uk/44065/ Design and elaboration of a tractable tricyclic scaffold to synthesize druglike inhibitors of dipeptidyl peptidase-4 (DPP-4), antagonists of the C–C Chemokine Receptor Type 5 (CCR5), and highly potent and selective phosphoinositol-3 Kinase δ (PI3Kδ) inhibitors Schwehm, Carolin Kellam, Barrie Garces, Aimie Hill, Stephen J. Kindon, Nicholas Bradshaw, Tracey D. Li, Jin Macdonald, Simon J.F. Rowedder, James E. Stoddart, Leigh A. Stocks, Michael A novel molecular scaffold has been synthesized, and its incorporation into new analogues of biologically active molecules across multiple target classes will be discussed. In these studies, we have shown use of the tricyclic scaffold to synthesize potent inhibitors of the serine peptidase DPP-4, antagonists of the CCR5 receptor, and highly potent and selective PI3K δ isoform inhibitors. We also describe the predicted physicochemical properties of the resulting inhibitors and conclude that the tractable molecular scaffold could have potential application in future drug discovery programs. American Chemical Society 2017-01-27 Article PeerReviewed Schwehm, Carolin, Kellam, Barrie, Garces, Aimie, Hill, Stephen J., Kindon, Nicholas, Bradshaw, Tracey D., Li, Jin, Macdonald, Simon J.F., Rowedder, James E., Stoddart, Leigh A. and Stocks, Michael (2017) Design and elaboration of a tractable tricyclic scaffold to synthesize druglike inhibitors of dipeptidyl peptidase-4 (DPP-4), antagonists of the C–C Chemokine Receptor Type 5 (CCR5), and highly potent and selective phosphoinositol-3 Kinase δ (PI3Kδ) inhibitors. Journal of Medicinal Chemistry, 60 (4). pp. 1534-1554. ISSN 1520-4804 http://pubs.acs.org/doi/abs/10.1021/acs.jmedchem.6b01801 doi:10.1021/acs.jmedchem.6b01801 doi:10.1021/acs.jmedchem.6b01801
spellingShingle Schwehm, Carolin
Kellam, Barrie
Garces, Aimie
Hill, Stephen J.
Kindon, Nicholas
Bradshaw, Tracey D.
Li, Jin
Macdonald, Simon J.F.
Rowedder, James E.
Stoddart, Leigh A.
Stocks, Michael
Design and elaboration of a tractable tricyclic scaffold to synthesize druglike inhibitors of dipeptidyl peptidase-4 (DPP-4), antagonists of the C–C Chemokine Receptor Type 5 (CCR5), and highly potent and selective phosphoinositol-3 Kinase δ (PI3Kδ) inhibitors
title Design and elaboration of a tractable tricyclic scaffold to synthesize druglike inhibitors of dipeptidyl peptidase-4 (DPP-4), antagonists of the C–C Chemokine Receptor Type 5 (CCR5), and highly potent and selective phosphoinositol-3 Kinase δ (PI3Kδ) inhibitors
title_full Design and elaboration of a tractable tricyclic scaffold to synthesize druglike inhibitors of dipeptidyl peptidase-4 (DPP-4), antagonists of the C–C Chemokine Receptor Type 5 (CCR5), and highly potent and selective phosphoinositol-3 Kinase δ (PI3Kδ) inhibitors
title_fullStr Design and elaboration of a tractable tricyclic scaffold to synthesize druglike inhibitors of dipeptidyl peptidase-4 (DPP-4), antagonists of the C–C Chemokine Receptor Type 5 (CCR5), and highly potent and selective phosphoinositol-3 Kinase δ (PI3Kδ) inhibitors
title_full_unstemmed Design and elaboration of a tractable tricyclic scaffold to synthesize druglike inhibitors of dipeptidyl peptidase-4 (DPP-4), antagonists of the C–C Chemokine Receptor Type 5 (CCR5), and highly potent and selective phosphoinositol-3 Kinase δ (PI3Kδ) inhibitors
title_short Design and elaboration of a tractable tricyclic scaffold to synthesize druglike inhibitors of dipeptidyl peptidase-4 (DPP-4), antagonists of the C–C Chemokine Receptor Type 5 (CCR5), and highly potent and selective phosphoinositol-3 Kinase δ (PI3Kδ) inhibitors
title_sort design and elaboration of a tractable tricyclic scaffold to synthesize druglike inhibitors of dipeptidyl peptidase-4 (dpp-4), antagonists of the c–c chemokine receptor type 5 (ccr5), and highly potent and selective phosphoinositol-3 kinase δ (pi3kδ) inhibitors
url https://eprints.nottingham.ac.uk/44065/
https://eprints.nottingham.ac.uk/44065/
https://eprints.nottingham.ac.uk/44065/