Resonance-enhanced multiphoton ionization (REMPI) spectroscopy of p-chlorofluorobenzene

The S1 ← S0 (A ~ 1B2 ← X~ 1A1) electronic transition of para-chlorofluorobenzene has been investigated using resonance-enhanced multiphoton ionization (REMPI) spectroscopy. Assignment of the vibrational structure has been achieved by comparison with corresponding spectra of related molecules, via qu...

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Bibliographic Details
Main Authors: Tuttle, William D., Gardner, Adrian M., Wright, Timothy G.
Format: Article
Published: Elsevier 2017
Online Access:https://eprints.nottingham.ac.uk/44053/
Description
Summary:The S1 ← S0 (A ~ 1B2 ← X~ 1A1) electronic transition of para-chlorofluorobenzene has been investigated using resonance-enhanced multiphoton ionization (REMPI) spectroscopy. Assignment of the vibrational structure has been achieved by comparison with corresponding spectra of related molecules, via quantum chemical calculations, and via shifts in bands between the spectra of the 35Cl and 37Cl isotopologues. In addition, we have also partially reassigned a previously-published spectrum of para-dichlorobenzene.