Searching for interstellar C60+ using a new method for high signal-to-noise HST/STIS spectroscopy

Due to recent advances in laboratory spectroscopy, the first optical detection of a very large molecule has been claimed in the diffuse interstellar medium (ISM): ${{\rm{C}}}_{60}^{+}$ (ionized Buckminsterfullerene). Confirming the presence of this molecule would have significant implications regard...

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Main Authors: Cordiner, M.A., Cox, N.L.J., Lallement, R., Najarro, F., Cami, J., Gull, T.R., Foing, B.H., Linnartz, H., Proffitt, C.R., Sarre, Peter, Charnley, S.B.
Format: Article
Language:English
Published: American Astronomical Society 2017
Subjects:
Online Access:https://eprints.nottingham.ac.uk/43860/
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author Cordiner, M.A.
Cox, N.L.J.
Lallement, R.
Najarro, F.
Cami, J.
Gull, T.R.
Foing, B.H.
Linnartz, H.
Proffitt, C.R.
Sarre, Peter
Charnley, S.B.
author_facet Cordiner, M.A.
Cox, N.L.J.
Lallement, R.
Najarro, F.
Cami, J.
Gull, T.R.
Foing, B.H.
Linnartz, H.
Proffitt, C.R.
Sarre, Peter
Charnley, S.B.
author_sort Cordiner, M.A.
building Nottingham Research Data Repository
collection Online Access
description Due to recent advances in laboratory spectroscopy, the first optical detection of a very large molecule has been claimed in the diffuse interstellar medium (ISM): ${{\rm{C}}}_{60}^{+}$ (ionized Buckminsterfullerene). Confirming the presence of this molecule would have significant implications regarding the carbon budget and chemical complexity of the ISM. Here we present results from a new method for ultra-high signal-to-noise ratio (S/N) spectroscopy of background stars in the near-infrared (at wavelengths of 0.9–1 μm), using the Hubble Space Telescope (HST) Imaging Spectrograph (STIS) in a previously untested "STIS scan" mode. The use of HST provides the crucial benefit of eliminating the need for error-prone telluric-correction methods in the part of the spectrum where the ${{\rm{C}}}_{60}^{+}$ bands lie and where the terrestrial water vapor contamination is severe. Our STIS spectrum of the heavily reddened B0 supergiant star BD+63 1964 reaches an unprecedented S/N for this instrument (~600–800), allowing the detection of the diffuse interstellar band (DIB) at 9577 Å attributed to ${{\rm{C}}}_{60}^{+}$, as well as new DIBs in the near-IR. Unfortunately, the presence of overlapping stellar lines, and the unexpected weakness of the ${{\rm{C}}}_{60}^{+}$ bands in this sightline, prevents conclusive detection of the weaker ${{\rm{C}}}_{60}^{+}$ bands. A probable correlation between the 9577 Å DIB strength and interstellar radiation field is identified, which suggests that more strongly irradiated interstellar sightlines will provide the optimal targets for future ${{\rm{C}}}_{60}^{+}$ searches.
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spelling nottingham-438602017-10-12T23:54:50Z https://eprints.nottingham.ac.uk/43860/ Searching for interstellar C60+ using a new method for high signal-to-noise HST/STIS spectroscopy Cordiner, M.A. Cox, N.L.J. Lallement, R. Najarro, F. Cami, J. Gull, T.R. Foing, B.H. Linnartz, H. Proffitt, C.R. Sarre, Peter Charnley, S.B. Due to recent advances in laboratory spectroscopy, the first optical detection of a very large molecule has been claimed in the diffuse interstellar medium (ISM): ${{\rm{C}}}_{60}^{+}$ (ionized Buckminsterfullerene). Confirming the presence of this molecule would have significant implications regarding the carbon budget and chemical complexity of the ISM. Here we present results from a new method for ultra-high signal-to-noise ratio (S/N) spectroscopy of background stars in the near-infrared (at wavelengths of 0.9–1 μm), using the Hubble Space Telescope (HST) Imaging Spectrograph (STIS) in a previously untested "STIS scan" mode. The use of HST provides the crucial benefit of eliminating the need for error-prone telluric-correction methods in the part of the spectrum where the ${{\rm{C}}}_{60}^{+}$ bands lie and where the terrestrial water vapor contamination is severe. Our STIS spectrum of the heavily reddened B0 supergiant star BD+63 1964 reaches an unprecedented S/N for this instrument (~600–800), allowing the detection of the diffuse interstellar band (DIB) at 9577 Å attributed to ${{\rm{C}}}_{60}^{+}$, as well as new DIBs in the near-IR. Unfortunately, the presence of overlapping stellar lines, and the unexpected weakness of the ${{\rm{C}}}_{60}^{+}$ bands in this sightline, prevents conclusive detection of the weaker ${{\rm{C}}}_{60}^{+}$ bands. A probable correlation between the 9577 Å DIB strength and interstellar radiation field is identified, which suggests that more strongly irradiated interstellar sightlines will provide the optimal targets for future ${{\rm{C}}}_{60}^{+}$ searches. American Astronomical Society 2017-06-23 Article PeerReviewed application/pdf en https://eprints.nottingham.ac.uk/43860/8/Interstellar.pdf Cordiner, M.A., Cox, N.L.J., Lallement, R., Najarro, F., Cami, J., Gull, T.R., Foing, B.H., Linnartz, H., Proffitt, C.R., Sarre, Peter and Charnley, S.B. (2017) Searching for interstellar C60+ using a new method for high signal-to-noise HST/STIS spectroscopy. Astrophysical Journal Letters, 843 (1). L2/1-L2/6. ISSN 2041-8213 Instrumentation: spectrographs ISM: molecules Line: identification Techniques: spectroscopic http://iopscience.iop.org/article/10.3847/2041-8213/aa78f7/meta;jsessionid=1BA9F62A98399C1E536259D74BD073F0.c1.iopscience.cld.iop.org doi:10.3847/2041-8213/aa78f7 doi:10.3847/2041-8213/aa78f7
spellingShingle Instrumentation: spectrographs
ISM: molecules
Line: identification
Techniques: spectroscopic
Cordiner, M.A.
Cox, N.L.J.
Lallement, R.
Najarro, F.
Cami, J.
Gull, T.R.
Foing, B.H.
Linnartz, H.
Proffitt, C.R.
Sarre, Peter
Charnley, S.B.
Searching for interstellar C60+ using a new method for high signal-to-noise HST/STIS spectroscopy
title Searching for interstellar C60+ using a new method for high signal-to-noise HST/STIS spectroscopy
title_full Searching for interstellar C60+ using a new method for high signal-to-noise HST/STIS spectroscopy
title_fullStr Searching for interstellar C60+ using a new method for high signal-to-noise HST/STIS spectroscopy
title_full_unstemmed Searching for interstellar C60+ using a new method for high signal-to-noise HST/STIS spectroscopy
title_short Searching for interstellar C60+ using a new method for high signal-to-noise HST/STIS spectroscopy
title_sort searching for interstellar c60+ using a new method for high signal-to-noise hst/stis spectroscopy
topic Instrumentation: spectrographs
ISM: molecules
Line: identification
Techniques: spectroscopic
url https://eprints.nottingham.ac.uk/43860/
https://eprints.nottingham.ac.uk/43860/
https://eprints.nottingham.ac.uk/43860/