Analytic solutions of the Rolie Poly model in time-dependent shear

We consider shear flows that comprise of step changes in the shear rate. For these flows, we derive analytic solutions of the Rolie-Poly constitutive equation. Our method involves piecing together solutions for constant rate shear in a variety of flow rate regimes. We obtain solutions for interrupte...

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Main Authors: Holroyd, George A.J., Martin, Samuel J., Graham, Richard Stuart
Format: Article
Published: AIP Publishing 2017
Online Access:https://eprints.nottingham.ac.uk/43578/
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author Holroyd, George A.J.
Martin, Samuel J.
Graham, Richard Stuart
author_facet Holroyd, George A.J.
Martin, Samuel J.
Graham, Richard Stuart
author_sort Holroyd, George A.J.
building Nottingham Research Data Repository
collection Online Access
description We consider shear flows that comprise of step changes in the shear rate. For these flows, we derive analytic solutions of the Rolie-Poly constitutive equation. Our method involves piecing together solutions for constant rate shear in a variety of flow rate regimes. We obtain solutions for interrupted shear, recoverable strain and non-linear relaxation following cessation of flow. Whenever strong flow is present we neglect reptation, as other mechanisms dominate and for interrupted shear our solution is approximate as we neglect convective constraint release. Our analytic solutions provide new insight in several ways. These include revealing the mechanism of some experimental features of these flows; suggesting a method to extract the polymer contribution to the normal stress in the velocity gradient direction (σyy) from shear stress measurements alone; and a method to isolate the influence of convective constraint release (CCR) from damping function measurements. We also run complementary GLaMM model calculations to verify that insight from our analytic approach translates to this more detailed model.
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spelling nottingham-435782020-05-04T18:55:02Z https://eprints.nottingham.ac.uk/43578/ Analytic solutions of the Rolie Poly model in time-dependent shear Holroyd, George A.J. Martin, Samuel J. Graham, Richard Stuart We consider shear flows that comprise of step changes in the shear rate. For these flows, we derive analytic solutions of the Rolie-Poly constitutive equation. Our method involves piecing together solutions for constant rate shear in a variety of flow rate regimes. We obtain solutions for interrupted shear, recoverable strain and non-linear relaxation following cessation of flow. Whenever strong flow is present we neglect reptation, as other mechanisms dominate and for interrupted shear our solution is approximate as we neglect convective constraint release. Our analytic solutions provide new insight in several ways. These include revealing the mechanism of some experimental features of these flows; suggesting a method to extract the polymer contribution to the normal stress in the velocity gradient direction (σyy) from shear stress measurements alone; and a method to isolate the influence of convective constraint release (CCR) from damping function measurements. We also run complementary GLaMM model calculations to verify that insight from our analytic approach translates to this more detailed model. AIP Publishing 2017-07-10 Article PeerReviewed Holroyd, George A.J., Martin, Samuel J. and Graham, Richard Stuart (2017) Analytic solutions of the Rolie Poly model in time-dependent shear. Journal of Rheology, 61 (5). pp. 859-870. ISSN 1520-8516 http://sor.scitation.org/doi/10.1122/1.4990639 doi:10.1122/1.4990639 doi:10.1122/1.4990639
spellingShingle Holroyd, George A.J.
Martin, Samuel J.
Graham, Richard Stuart
Analytic solutions of the Rolie Poly model in time-dependent shear
title Analytic solutions of the Rolie Poly model in time-dependent shear
title_full Analytic solutions of the Rolie Poly model in time-dependent shear
title_fullStr Analytic solutions of the Rolie Poly model in time-dependent shear
title_full_unstemmed Analytic solutions of the Rolie Poly model in time-dependent shear
title_short Analytic solutions of the Rolie Poly model in time-dependent shear
title_sort analytic solutions of the rolie poly model in time-dependent shear
url https://eprints.nottingham.ac.uk/43578/
https://eprints.nottingham.ac.uk/43578/
https://eprints.nottingham.ac.uk/43578/