A second-generation ligand for the enantioselective rhodium-catalyzed addition of arylboronic acids to alkenylazaarenes
A 2,4,6-trialkylanilide-containing chiral diene has been identified as a superior ligand for the enantioselective rhodiumcatalyzed arylation of alkenylazaarenes with arylboronic acids.
| Main Authors: | Roy, Iain D., Burns, Alan R., Pattison, Graham, Michel, Boris, Parker, Alexandra J., Lam, Hon Wai |
|---|---|
| Format: | Article |
| Published: |
Royal Society of Chemistry
2014
|
| Online Access: | https://eprints.nottingham.ac.uk/43481/ |
Similar Items
Enantioselective rhodium-catalyzed coupling of arylboronic acids, 1,3-enynes, and Imines by alkenyl-to-allyl 1,4-rhodium(I) migration
by: Callingham, Michael, et al.
Published: (2017)
by: Callingham, Michael, et al.
Published: (2017)
Enantioselective synthesis of allylboronates and allylic alcohols by copper-catalyzed 1,6-boration
by: Luo, Yunfei, et al.
Published: (2014)
by: Luo, Yunfei, et al.
Published: (2014)
Synthesis of spirocyclic enones by rhodium-catalyzed dearomatizing oxidative annulation of 2-alkenylphenols with alkynes and enynes
by: Kujawa, Szymon, et al.
Published: (2014)
by: Kujawa, Szymon, et al.
Published: (2014)
Enantioselective nickel-catalyzed arylative intramolecular 1,4allylations
by: Nguyen, Thi Le Nhon, et al.
Published: (2018)
by: Nguyen, Thi Le Nhon, et al.
Published: (2018)
Towards Enantioselective Rhodium-Catalysed Addition of Alkenylboron Species to Azinium Salts
by: Bentley, K.B.
Published: (2021)
by: Bentley, K.B.
Published: (2021)
Switchable synthesis of Z-homoallylic boronates and E-allylic
boronates by enantioselective copper-catalyzed 1,6-boration
by: Luo, Yunfei, et al.
Published: (2018)
by: Luo, Yunfei, et al.
Published: (2018)
Rhodium-catalyzed oxidative C–H allylation of benzamides
with 1,3-dienes by allyl-to-allyl 1,4-Rh(III) migration
by: Korkis, Stamatis E., et al.
Published: (2016)
by: Korkis, Stamatis E., et al.
Published: (2016)
Enantioselective copper-catalyzed reductive coupling of vinylazaarenes with N-Boc aldimines
by: Choi, Bonnie, et al.
Published: (2015)
by: Choi, Bonnie, et al.
Published: (2015)
Chain walking of allylrhodium species towards esters during
rhodium-catalyzed nucleophilic allylations of imines
by: Martínez, Jose I., et al.
Published: (2015)
by: Martínez, Jose I., et al.
Published: (2015)
Enantioselective synthesis of chiral cyclopent-2-enones by nickel-catalyzed desymmetrization of malonate esters
by: Karad, Somnath Narayan, et al.
Published: (2018)
by: Karad, Somnath Narayan, et al.
Published: (2018)
Enantioselective nickel-catalyzed anti-carbometallative cyclizations
of alkynyl electrophiles enabled by reversible alkenylnickel E/Z
isomerization
by: Clarke, Christopher, et al.
Published: (2016)
by: Clarke, Christopher, et al.
Published: (2016)
Enantioselective nickel-catalyzed intramolecular allylic alkenylations enabled by reversible alkenylnickel E/Z isomerization
by: Yap, Connor, et al.
Published: (2017)
by: Yap, Connor, et al.
Published: (2017)
Enantioselective nickel-catalyzed arylative intramolecular allylations of allenyl electrophiles
by: NGUYEN, THI LE NHON
Published: (2020)
by: NGUYEN, THI LE NHON
Published: (2020)
Lipase catalyzed enantioselective esterification reaction to produce chiral products
by: Basri, Mahiran, et al.
Published: (1999)
by: Basri, Mahiran, et al.
Published: (1999)
Possible origin of electronic effects in Rh(I)-catalyzed enantioselective hydrogenation
by: Wu, Hai-Chen, et al.
Published: (2009)
by: Wu, Hai-Chen, et al.
Published: (2009)
Photocatalytic hydroxylation of arylboronic acids using continuous flow reactors
by: Penders, Inès G. T. M., et al.
Published: (2014)
by: Penders, Inès G. T. M., et al.
Published: (2014)
C=N-containing azaarenes as activating groups in enantioselective catalysis
by: Best, Daniel, et al.
Published: (2013)
by: Best, Daniel, et al.
Published: (2013)
X-ray photoelectron spectroscopy as a probe of rhodium-ligand interaction in ionic liquids
by: Men, Shuan, et al.
Published: (2016)
by: Men, Shuan, et al.
Published: (2016)
Rhodium-catalysed arylative cyclisations of malonate esters by 1,4-rhodium migration
by: O'Brien, Luke
Published: (2019)
by: O'Brien, Luke
Published: (2019)
One-carbon oxidative annulations of 1,3-enynes by catalytic C–H functionalization and 1,4-rhodium(III) migration
by: Dooley, Johnathon D., et al.
Published: (2018)
by: Dooley, Johnathon D., et al.
Published: (2018)
Versatile C(sp2)−C(sp3) ligand couplings of sulfoxides for the enantioselective synthesis of diarylalkanes
by: Dean, William Michael, et al.
Published: (2016)
by: Dean, William Michael, et al.
Published: (2016)
Reductive Coupling of Diynes at Rhodium Gives Fluorescent Rhodacyclopentadienes or Phosphorescent Rhodium 2,2'-Biphenyl Complexes
by: Sieck, C., et al.
Published: (2016)
by: Sieck, C., et al.
Published: (2016)
Structural And Magnetic Properties Of Rhodium Clusters
by: Soon,, Yee Yeen
Published: (2017)
by: Soon,, Yee Yeen
Published: (2017)
Enantioselective immobilized lipase
by: Basri, Mahiran, et al.
Published: (2008)
by: Basri, Mahiran, et al.
Published: (2008)
Polymerizations Mediated by Well-Defined Rhodium Complexes
by: Tan, Nicholas Sheng Loong, et al.
Published: (2020)
by: Tan, Nicholas Sheng Loong, et al.
Published: (2020)
Study of the Interface between Rhodium and Carbon Nanotubes
by: Suarez-Martinez, Irene, et al.
Published: (2010)
by: Suarez-Martinez, Irene, et al.
Published: (2010)
Ligands modulate reaction pathway in the hydrogenation
of 4-Nitrophenol catalyzed by gold nanoclusters
by: Nasaruddin, Ricca Rahman, et al.
Published: (2018)
by: Nasaruddin, Ricca Rahman, et al.
Published: (2018)
Asymmetric transition metal-catalyzed alkyl addition to imines with chiral phosphine ligands
by: El Hajjaji, Samir
Published: (2010)
by: El Hajjaji, Samir
Published: (2010)
The Enantioselective Generation of Bridgehead Enolates
by: Kirk, Douglas Thomas
Published: (2003)
by: Kirk, Douglas Thomas
Published: (2003)
Controlled Polymerisation of Arylacetylenes with Well-Defined Rhodium Catalysts
by: Tan, Nicholas Sheng Loong
Published: (2020)
by: Tan, Nicholas Sheng Loong
Published: (2020)
Copper-catalyzed borylative coupling of vinylazaarenes and N-Boc imines
by: Smith, Joshua J., et al.
Published: (2016)
by: Smith, Joshua J., et al.
Published: (2016)
Enantioselective binding of additives to chiral crystals
by: Carter, D., et al.
Published: (2012)
by: Carter, D., et al.
Published: (2012)
Nickel-catalysed enantioselective arylative cyclisations
by: Clarke, Christopher
Published: (2019)
by: Clarke, Christopher
Published: (2019)
A theoretical study of the activity in Rh-catalyzed
hydroformylation: the origin of the enhanced
activity of the π-acceptor phosphinine ligand
by: Aguado-Ullate, Sonia, et al.
Published: (2014)
by: Aguado-Ullate, Sonia, et al.
Published: (2014)
Arranging an enantioselective aza-[2,3]-Wittig rearrangement
by: Davies, Elizabeth Anne
Published: (2009)
by: Davies, Elizabeth Anne
Published: (2009)
Enzymatic enantioselective acylation of sterically aromatic secondary alcohol
by: Chua, Lee Suan, et al.
Published: (2005)
by: Chua, Lee Suan, et al.
Published: (2005)
Oxidative addition of (bromoethynyl) benzene to κ 2-acetylacetonatobis (trimethylphosphine) rhodium (I)
by: Marie-Hélèn, Thibault, et al.
Published: (2013)
by: Marie-Hélèn, Thibault, et al.
Published: (2013)
Oxidative addition of (bromoethynyl)benzene to κ2- acetylacetonatobis(trimethylphosphine)rhodium(I)
by: Marie-Hélène, Thibault, et al.
Published: (2013)
by: Marie-Hélène, Thibault, et al.
Published: (2013)
Ligand recognition by the major urinary protein
by: Roy, Julie
Published: (2012)
by: Roy, Julie
Published: (2012)
Hydroformylation of 1-octene using rhodium-phosphite catalyst in a thermomorphic solvent system
by: M.S., Shaharun, et al.
Published: (2010)
by: M.S., Shaharun, et al.
Published: (2010)
Similar Items
-
Enantioselective rhodium-catalyzed coupling of arylboronic acids, 1,3-enynes, and Imines by alkenyl-to-allyl 1,4-rhodium(I) migration
by: Callingham, Michael, et al.
Published: (2017) -
Enantioselective synthesis of allylboronates and allylic alcohols by copper-catalyzed 1,6-boration
by: Luo, Yunfei, et al.
Published: (2014) -
Synthesis of spirocyclic enones by rhodium-catalyzed dearomatizing oxidative annulation of 2-alkenylphenols with alkynes and enynes
by: Kujawa, Szymon, et al.
Published: (2014) -
Enantioselective nickel-catalyzed arylative intramolecular 1,4allylations
by: Nguyen, Thi Le Nhon, et al.
Published: (2018) -
Towards Enantioselective Rhodium-Catalysed Addition of Alkenylboron Species to Azinium Salts
by: Bentley, K.B.
Published: (2021)