Rapid nano-gram scale screening method of micro-arrays to evaluate drug-polymer blends using high-throughput printing technology

A miniaturized, high-throughput assay was optimized to screen polymer-drug solid dispersions using a 2-D Ink-jet printer. By simply printing nanoliter amounts of polymer and drug solutions onto an inert surface, drug:polymer micro-dots of tunable composition were produced in an easily-addressable mi...

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Main Authors: Taresco, Vincenzo, Louzao, Iria, Scurr, David J., Turpin, Eleanor R., Laughton, Charles A., Alexander, Cameron, Burley, Jonathan C., Garnett, Martin
Format: Article
Published: American Chemical Society 2017
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Online Access:https://eprints.nottingham.ac.uk/42908/
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author Taresco, Vincenzo
Louzao, Iria
Scurr, David J.
Turpin, Eleanor R.
Laughton, Charles A.
Alexander, Cameron
Burley, Jonathan C.
Garnett, Martin
author_facet Taresco, Vincenzo
Louzao, Iria
Scurr, David J.
Turpin, Eleanor R.
Laughton, Charles A.
Alexander, Cameron
Burley, Jonathan C.
Garnett, Martin
author_sort Taresco, Vincenzo
building Nottingham Research Data Repository
collection Online Access
description A miniaturized, high-throughput assay was optimized to screen polymer-drug solid dispersions using a 2-D Ink-jet printer. By simply printing nanoliter amounts of polymer and drug solutions onto an inert surface, drug:polymer micro-dots of tunable composition were produced in an easily-addressable micro-array format. The amount of material printed for each dried spot ranged from 25 ng to 650 ng. These arrays were used to assess the stability of drug:polymer dispersions with respect to recrystallization, using polarized light microscopy. One array with a panel of 6 drugs formulated at different ratios with Poly (vinylpyrrolidone-vinyl acetate) copolymer (PVPVA) was developed to estimate a possible bulk (gram-scale) approximation threshold from the final printed nano amount of formulation. Another array was printed at a fixed final amount of material to establish a literature comparison of one drug formulated with different commercial polymers for validation. This new approach may offer significant efficiency in pharmaceutical formulation screening, with each experiment in the nano-micro-array format requiring from 3 up to 6 orders of magnitude lower amounts of sample than conventional screening methods.
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publishDate 2017
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spelling nottingham-429082020-05-04T18:45:37Z https://eprints.nottingham.ac.uk/42908/ Rapid nano-gram scale screening method of micro-arrays to evaluate drug-polymer blends using high-throughput printing technology Taresco, Vincenzo Louzao, Iria Scurr, David J. Turpin, Eleanor R. Laughton, Charles A. Alexander, Cameron Burley, Jonathan C. Garnett, Martin A miniaturized, high-throughput assay was optimized to screen polymer-drug solid dispersions using a 2-D Ink-jet printer. By simply printing nanoliter amounts of polymer and drug solutions onto an inert surface, drug:polymer micro-dots of tunable composition were produced in an easily-addressable micro-array format. The amount of material printed for each dried spot ranged from 25 ng to 650 ng. These arrays were used to assess the stability of drug:polymer dispersions with respect to recrystallization, using polarized light microscopy. One array with a panel of 6 drugs formulated at different ratios with Poly (vinylpyrrolidone-vinyl acetate) copolymer (PVPVA) was developed to estimate a possible bulk (gram-scale) approximation threshold from the final printed nano amount of formulation. Another array was printed at a fixed final amount of material to establish a literature comparison of one drug formulated with different commercial polymers for validation. This new approach may offer significant efficiency in pharmaceutical formulation screening, with each experiment in the nano-micro-array format requiring from 3 up to 6 orders of magnitude lower amounts of sample than conventional screening methods. American Chemical Society 2017-05-14 Article PeerReviewed Taresco, Vincenzo, Louzao, Iria, Scurr, David J., Turpin, Eleanor R., Laughton, Charles A., Alexander, Cameron, Burley, Jonathan C. and Garnett, Martin (2017) Rapid nano-gram scale screening method of micro-arrays to evaluate drug-polymer blends using high-throughput printing technology. Molecular Pharmaceutics, 14 (6). pp. 2079-2087. ISSN 1543-8384 High throughput array Ink-jet printing Amorphous dispersion Recrystallisation Polarizing microscopy http://pubs.acs.org/doi/abs/10.1021/acs.molpharmaceut.7b00182 doi:10.1021/acs.molpharmaceut.7b00182 doi:10.1021/acs.molpharmaceut.7b00182
spellingShingle High throughput array
Ink-jet printing
Amorphous dispersion
Recrystallisation
Polarizing microscopy
Taresco, Vincenzo
Louzao, Iria
Scurr, David J.
Turpin, Eleanor R.
Laughton, Charles A.
Alexander, Cameron
Burley, Jonathan C.
Garnett, Martin
Rapid nano-gram scale screening method of micro-arrays to evaluate drug-polymer blends using high-throughput printing technology
title Rapid nano-gram scale screening method of micro-arrays to evaluate drug-polymer blends using high-throughput printing technology
title_full Rapid nano-gram scale screening method of micro-arrays to evaluate drug-polymer blends using high-throughput printing technology
title_fullStr Rapid nano-gram scale screening method of micro-arrays to evaluate drug-polymer blends using high-throughput printing technology
title_full_unstemmed Rapid nano-gram scale screening method of micro-arrays to evaluate drug-polymer blends using high-throughput printing technology
title_short Rapid nano-gram scale screening method of micro-arrays to evaluate drug-polymer blends using high-throughput printing technology
title_sort rapid nano-gram scale screening method of micro-arrays to evaluate drug-polymer blends using high-throughput printing technology
topic High throughput array
Ink-jet printing
Amorphous dispersion
Recrystallisation
Polarizing microscopy
url https://eprints.nottingham.ac.uk/42908/
https://eprints.nottingham.ac.uk/42908/
https://eprints.nottingham.ac.uk/42908/