Antioxidant properties of novel dimers derived from natural β‑elemene through inhibiting H2O2‑induced apoptosis

A series of novel β-elemene dimer derivatives were synthesized and evaluated for their antioxidant activities. The results indicated that most of the target compounds showed more potent cytoprotective effects than positive control vitamin E. In particular, dimer D5 exhibited the strongest antioxidan...

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Main Authors: Chen, Jichao, Wang, Ruifan, Wang, Tianyu, Ding, Qilong, Khalil, Aliahmad, Xu, Shengtao, Lin, Aijun, Yao, Hequan, Xie, Weijia, Zhu, Zheying, Xu, Jinyi
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Published: American Chemical Society 2017
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Online Access:https://eprints.nottingham.ac.uk/42901/
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author Chen, Jichao
Wang, Ruifan
Wang, Tianyu
Ding, Qilong
Khalil, Aliahmad
Xu, Shengtao
Lin, Aijun
Yao, Hequan
Xie, Weijia
Zhu, Zheying
Xu, Jinyi
author_facet Chen, Jichao
Wang, Ruifan
Wang, Tianyu
Ding, Qilong
Khalil, Aliahmad
Xu, Shengtao
Lin, Aijun
Yao, Hequan
Xie, Weijia
Zhu, Zheying
Xu, Jinyi
author_sort Chen, Jichao
building Nottingham Research Data Repository
collection Online Access
description A series of novel β-elemene dimer derivatives were synthesized and evaluated for their antioxidant activities. The results indicated that most of the target compounds showed more potent cytoprotective effects than positive control vitamin E. In particular, dimer D5 exhibited the strongest antioxidant activity, which was significantly superior to the active compound D1 obtained in our previous study. Besides, D5 did not produce obvious cytotoxicity in normal human umbilical vein endothelial cells (HUVECs) and increased the viability of HUVECs injured by H2O2 in a concentration-dependent manner. Further studies suggested that the cytoprotective action of D5 might be mediated, at least in part, by increasing the intracellular superoxide dismutase activity and nitric oxide secretion as well as decreasing the intracellular malonyldialdehyde content and lactate dehydrogenase release. Furthermore, D5 observably inhibited ROS generation and prevented H2O2-induced apoptosis in HUVECs possibly via inhibiting the activation of the MAPK signaling pathway.
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institution University of Nottingham Malaysia Campus
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last_indexed 2025-11-14T19:50:30Z
publishDate 2017
publisher American Chemical Society
recordtype eprints
repository_type Digital Repository
spelling nottingham-429012020-05-04T18:37:25Z https://eprints.nottingham.ac.uk/42901/ Antioxidant properties of novel dimers derived from natural β‑elemene through inhibiting H2O2‑induced apoptosis Chen, Jichao Wang, Ruifan Wang, Tianyu Ding, Qilong Khalil, Aliahmad Xu, Shengtao Lin, Aijun Yao, Hequan Xie, Weijia Zhu, Zheying Xu, Jinyi A series of novel β-elemene dimer derivatives were synthesized and evaluated for their antioxidant activities. The results indicated that most of the target compounds showed more potent cytoprotective effects than positive control vitamin E. In particular, dimer D5 exhibited the strongest antioxidant activity, which was significantly superior to the active compound D1 obtained in our previous study. Besides, D5 did not produce obvious cytotoxicity in normal human umbilical vein endothelial cells (HUVECs) and increased the viability of HUVECs injured by H2O2 in a concentration-dependent manner. Further studies suggested that the cytoprotective action of D5 might be mediated, at least in part, by increasing the intracellular superoxide dismutase activity and nitric oxide secretion as well as decreasing the intracellular malonyldialdehyde content and lactate dehydrogenase release. Furthermore, D5 observably inhibited ROS generation and prevented H2O2-induced apoptosis in HUVECs possibly via inhibiting the activation of the MAPK signaling pathway. American Chemical Society 2017-03-13 Article PeerReviewed Chen, Jichao, Wang, Ruifan, Wang, Tianyu, Ding, Qilong, Khalil, Aliahmad, Xu, Shengtao, Lin, Aijun, Yao, Hequan, Xie, Weijia, Zhu, Zheying and Xu, Jinyi (2017) Antioxidant properties of novel dimers derived from natural β‑elemene through inhibiting H2O2‑induced apoptosis. ACS Medicinal Chemistry Letters, 8 (4). pp. 443-448. ISSN 1948-5875 antioxidant activity; apoptosis; dimer; MAPK pathway; β-Elemene http://pubs.acs.org/doi/abs/10.1021/acsmedchemlett.7b00035 doi:10.1021/acsmedchemlett.7b00035 doi:10.1021/acsmedchemlett.7b00035
spellingShingle antioxidant activity; apoptosis; dimer; MAPK pathway; β-Elemene
Chen, Jichao
Wang, Ruifan
Wang, Tianyu
Ding, Qilong
Khalil, Aliahmad
Xu, Shengtao
Lin, Aijun
Yao, Hequan
Xie, Weijia
Zhu, Zheying
Xu, Jinyi
Antioxidant properties of novel dimers derived from natural β‑elemene through inhibiting H2O2‑induced apoptosis
title Antioxidant properties of novel dimers derived from natural β‑elemene through inhibiting H2O2‑induced apoptosis
title_full Antioxidant properties of novel dimers derived from natural β‑elemene through inhibiting H2O2‑induced apoptosis
title_fullStr Antioxidant properties of novel dimers derived from natural β‑elemene through inhibiting H2O2‑induced apoptosis
title_full_unstemmed Antioxidant properties of novel dimers derived from natural β‑elemene through inhibiting H2O2‑induced apoptosis
title_short Antioxidant properties of novel dimers derived from natural β‑elemene through inhibiting H2O2‑induced apoptosis
title_sort antioxidant properties of novel dimers derived from natural β‑elemene through inhibiting h2o2‑induced apoptosis
topic antioxidant activity; apoptosis; dimer; MAPK pathway; β-Elemene
url https://eprints.nottingham.ac.uk/42901/
https://eprints.nottingham.ac.uk/42901/
https://eprints.nottingham.ac.uk/42901/