Arylative intramolecular allylation of ketones with 1,3-enynes enabled by catalytic alkenyl-to-allyl 1,4-Rh(I) migration

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Arylative intramolecular allylation of ketones with 1,3-enynes enabled by catalytic alkenyl-to-allyl 1,4-Rh(I) migration

Alkenyl-to-allyl 1,4-Rh(I) migration enables the generation of nucleophilic allylrhodium(I) species by remote C–H activation. This new mode of reactivity was employed in the diastereoselective reaction of arylboron reagents with substrates containing a 1,3-enyne tethered to a ketone, to give product...

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Bibliographic Details
Main Authors:	Partridge, Benjamin M., Callingham, Michael, Lewis, William, Lam, Hon Wai
Format:	Article
Published:	Wiley-VCH Verlag 2017
Online Access:	https://eprints.nottingham.ac.uk/42584/

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