A comprehensive review of Pt electrocatalysts for the oxygen reduction reaction: nanostructure, activity, mechanism and carbon support in PEM fuel cells

The sluggish rate of the oxygen reduction reaction (ORR) in proton exchange membrane (PEM) fuel cells has been a major challenge. Significantly increasing efforts have been made worldwide towards a highly active ORR catalyst with high durability. Among all the catalysts exploited, Pt electrocatalyst...

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Main Authors: Sui, Sheng, Wang, Xiaoying, Zhou, Xintong, Su, Yuehong, Riffat, Saffa, Liu, Chang-jun
Format: Article
Published: Royal Society of Chemistry 2017
Online Access:https://eprints.nottingham.ac.uk/40957/
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author Sui, Sheng
Wang, Xiaoying
Zhou, Xintong
Su, Yuehong
Riffat, Saffa
Liu, Chang-jun
author_facet Sui, Sheng
Wang, Xiaoying
Zhou, Xintong
Su, Yuehong
Riffat, Saffa
Liu, Chang-jun
author_sort Sui, Sheng
building Nottingham Research Data Repository
collection Online Access
description The sluggish rate of the oxygen reduction reaction (ORR) in proton exchange membrane (PEM) fuel cells has been a major challenge. Significantly increasing efforts have been made worldwide towards a highly active ORR catalyst with high durability. Among all the catalysts exploited, Pt electrocatalysts are still the best in terms of a comprehensive evaluation. The investigation of Pt-based ORR catalysts is necessary for a practical ORR catalyst with low Pt content. This paper reviews recent progress in the studies of the mechanism, nanostructure, size effect and carbon supports of Pt electrocatalysts for the ORR. The importance of the size and structure control of Pt ORR catalysts, related with carbon support materials, is indicated. The potential methods for such control are discussed. The progress in theoretical studies and in situ catalyst characterization are also discussed. Finally, challenges and future developments are addressed.
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publishDate 2017
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spelling nottingham-409572020-05-04T18:32:53Z https://eprints.nottingham.ac.uk/40957/ A comprehensive review of Pt electrocatalysts for the oxygen reduction reaction: nanostructure, activity, mechanism and carbon support in PEM fuel cells Sui, Sheng Wang, Xiaoying Zhou, Xintong Su, Yuehong Riffat, Saffa Liu, Chang-jun The sluggish rate of the oxygen reduction reaction (ORR) in proton exchange membrane (PEM) fuel cells has been a major challenge. Significantly increasing efforts have been made worldwide towards a highly active ORR catalyst with high durability. Among all the catalysts exploited, Pt electrocatalysts are still the best in terms of a comprehensive evaluation. The investigation of Pt-based ORR catalysts is necessary for a practical ORR catalyst with low Pt content. This paper reviews recent progress in the studies of the mechanism, nanostructure, size effect and carbon supports of Pt electrocatalysts for the ORR. The importance of the size and structure control of Pt ORR catalysts, related with carbon support materials, is indicated. The potential methods for such control are discussed. The progress in theoretical studies and in situ catalyst characterization are also discussed. Finally, challenges and future developments are addressed. Royal Society of Chemistry 2017-03-01 Article PeerReviewed Sui, Sheng, Wang, Xiaoying, Zhou, Xintong, Su, Yuehong, Riffat, Saffa and Liu, Chang-jun (2017) A comprehensive review of Pt electrocatalysts for the oxygen reduction reaction: nanostructure, activity, mechanism and carbon support in PEM fuel cells. Journal of Materials Chemistry A, 5 (5). pp. 1808-1825. ISSN 2050-7496 http://pubs.rsc.org/en/Content/ArticleLanding/2017/TA/C6TA08580F#!divAbstract doi:10.1039/c6ta08580f doi:10.1039/c6ta08580f
spellingShingle Sui, Sheng
Wang, Xiaoying
Zhou, Xintong
Su, Yuehong
Riffat, Saffa
Liu, Chang-jun
A comprehensive review of Pt electrocatalysts for the oxygen reduction reaction: nanostructure, activity, mechanism and carbon support in PEM fuel cells
title A comprehensive review of Pt electrocatalysts for the oxygen reduction reaction: nanostructure, activity, mechanism and carbon support in PEM fuel cells
title_full A comprehensive review of Pt electrocatalysts for the oxygen reduction reaction: nanostructure, activity, mechanism and carbon support in PEM fuel cells
title_fullStr A comprehensive review of Pt electrocatalysts for the oxygen reduction reaction: nanostructure, activity, mechanism and carbon support in PEM fuel cells
title_full_unstemmed A comprehensive review of Pt electrocatalysts for the oxygen reduction reaction: nanostructure, activity, mechanism and carbon support in PEM fuel cells
title_short A comprehensive review of Pt electrocatalysts for the oxygen reduction reaction: nanostructure, activity, mechanism and carbon support in PEM fuel cells
title_sort comprehensive review of pt electrocatalysts for the oxygen reduction reaction: nanostructure, activity, mechanism and carbon support in pem fuel cells
url https://eprints.nottingham.ac.uk/40957/
https://eprints.nottingham.ac.uk/40957/
https://eprints.nottingham.ac.uk/40957/