A monomeric, heterobimetallic complex with an unsupported Mg−Fe bond

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A monomeric, heterobimetallic complex with an unsupported Mg−Fe bond

The phosphinimine, trimethylsilyl-substituted BIPM ligand [BIPM = bis(iminophosphorano)methanide] has been used to stabilise CH(Ph2PNSiMe3)2MgFe(η5-C5H5)(CO)2 (1), which is a structurally authenticated complex exhibiting a direct, unsupported bond between an alkaline earth metal and a transition met...

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Bibliographic Details
Main Authors:	Birchall, Christopher, Moxey, Graeme J., McMaster, Jonathan, Blake, Alexander J., Lewis, William, Kays, Deborah L.
Format:	Article
Published:	Elsevier 2017
Subjects:	Magnesium; Iron; Metal-metal interactions; N ligands; Density functional calculations
Online Access:	https://eprints.nottingham.ac.uk/40850/

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