Redox-active organic-inorganic hybrid polyoxometalate micelles

A redox-active hybrid organic-inorganic polyoxometalate surfactant showed solvent-dependent self-assembly to form nano-scale architectures. The supramolecular assemblies exhibited contrasting electronic structure and redox activity to their molecular building units, and were found to be stable under...

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Bibliographic Details
Main Authors: Kastner, Katharina, Kibler, Alexander J., Karjalainen, Erno, Fernandes, Jesum A., Sans, Victor, Newton, Graham
Format: Article
Published: Royal Society of Chemistry 2017
Online Access:https://eprints.nottingham.ac.uk/40553/
Description
Summary:A redox-active hybrid organic-inorganic polyoxometalate surfactant showed solvent-dependent self-assembly to form nano-scale architectures. The supramolecular assemblies exhibited contrasting electronic structure and redox activity to their molecular building units, and were found to be stable under electrochemical reduction and re-oxidation.