A multi-redox responsive cyanometalate-based metallogel
A tetrathiafulvalene (TTF) based tridentate ligand (-(4’-methyl-4,5-di-n-dodecylthylthiotetrathiafulvalene-5’-ylthio)-’-[tris-2,2,2-(1-pyrazolyl)ethoxy]-p-xylene) (L) with long-chain alkyl moieties was prepared in order to obtain a new multi-redox active gelator based on a mixed-metal octanuclear...
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| Format: | Article |
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Wiley-VCH Verlag
2017
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| Online Access: | https://eprints.nottingham.ac.uk/40375/ |
| _version_ | 1848796041235660800 |
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| author | Mitsumoto, Kiyotaka Cameron, Jamie Wei, Rong Jia Nishikawa, Hiroyuki Shiga, Takuya Nihei, Masayuki Newton, Graham Oshio, Hiroki |
| author_facet | Mitsumoto, Kiyotaka Cameron, Jamie Wei, Rong Jia Nishikawa, Hiroyuki Shiga, Takuya Nihei, Masayuki Newton, Graham Oshio, Hiroki |
| author_sort | Mitsumoto, Kiyotaka |
| building | Nottingham Research Data Repository |
| collection | Online Access |
| description | A tetrathiafulvalene (TTF) based tridentate ligand (-(4’-methyl-4,5-di-n-dodecylthylthiotetrathiafulvalene-5’-ylthio)-’-[tris-2,2,2-(1-pyrazolyl)ethoxy]-p-xylene) (L) with long-chain alkyl moieties was prepared in order to obtain a new multi-redox active gelator based on a mixed-metal octanuclear complex [FeIII4NiII4(CN)12(tp)4(L)4](BF4)4 (1). The magnetism, electrochemistry and gelation behaviour of 1 were studied and 1,2-dichlorobenzene solutions of 1 are shown to display thermoreversible gelation behaviour at room temperature. Furthermore, the gel phase of 1 is shown to undergo room-temperature gel-to-sol transformations induced by both the oxidation and reduction of the gelator complex by F4TCNQ or [FeII(Cp*)2], respectively. |
| first_indexed | 2025-11-14T19:41:40Z |
| format | Article |
| id | nottingham-40375 |
| institution | University of Nottingham Malaysia Campus |
| institution_category | Local University |
| last_indexed | 2025-11-14T19:41:40Z |
| publishDate | 2017 |
| publisher | Wiley-VCH Verlag |
| recordtype | eprints |
| repository_type | Digital Repository |
| spelling | nottingham-403752020-05-04T18:28:19Z https://eprints.nottingham.ac.uk/40375/ A multi-redox responsive cyanometalate-based metallogel Mitsumoto, Kiyotaka Cameron, Jamie Wei, Rong Jia Nishikawa, Hiroyuki Shiga, Takuya Nihei, Masayuki Newton, Graham Oshio, Hiroki A tetrathiafulvalene (TTF) based tridentate ligand (-(4’-methyl-4,5-di-n-dodecylthylthiotetrathiafulvalene-5’-ylthio)-’-[tris-2,2,2-(1-pyrazolyl)ethoxy]-p-xylene) (L) with long-chain alkyl moieties was prepared in order to obtain a new multi-redox active gelator based on a mixed-metal octanuclear complex [FeIII4NiII4(CN)12(tp)4(L)4](BF4)4 (1). The magnetism, electrochemistry and gelation behaviour of 1 were studied and 1,2-dichlorobenzene solutions of 1 are shown to display thermoreversible gelation behaviour at room temperature. Furthermore, the gel phase of 1 is shown to undergo room-temperature gel-to-sol transformations induced by both the oxidation and reduction of the gelator complex by F4TCNQ or [FeII(Cp*)2], respectively. Wiley-VCH Verlag 2017-02-01 Article PeerReviewed Mitsumoto, Kiyotaka, Cameron, Jamie, Wei, Rong Jia, Nishikawa, Hiroyuki, Shiga, Takuya, Nihei, Masayuki, Newton, Graham and Oshio, Hiroki (2017) A multi-redox responsive cyanometalate-based metallogel. Chemistry - a European Journal, 23 (7). pp. 1502-1506. ISSN 1521-3765 Stimuli-responsive Materials Sol-gel Redox Active Cyanometalate Supramolecular Chemistry http://onlinelibrary.wiley.com/doi/10.1002/chem.201605542/abstract doi:10.1002/chem.201605542 doi:10.1002/chem.201605542 |
| spellingShingle | Stimuli-responsive Materials Sol-gel Redox Active Cyanometalate Supramolecular Chemistry Mitsumoto, Kiyotaka Cameron, Jamie Wei, Rong Jia Nishikawa, Hiroyuki Shiga, Takuya Nihei, Masayuki Newton, Graham Oshio, Hiroki A multi-redox responsive cyanometalate-based metallogel |
| title | A multi-redox responsive cyanometalate-based metallogel |
| title_full | A multi-redox responsive cyanometalate-based metallogel |
| title_fullStr | A multi-redox responsive cyanometalate-based metallogel |
| title_full_unstemmed | A multi-redox responsive cyanometalate-based metallogel |
| title_short | A multi-redox responsive cyanometalate-based metallogel |
| title_sort | multi-redox responsive cyanometalate-based metallogel |
| topic | Stimuli-responsive Materials Sol-gel Redox Active Cyanometalate Supramolecular Chemistry |
| url | https://eprints.nottingham.ac.uk/40375/ https://eprints.nottingham.ac.uk/40375/ https://eprints.nottingham.ac.uk/40375/ |